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On Silylated Oxonium and Sulfonium Ions and Their Interaction with Weakly Coordinating Borate Anions
Attempts have been made to prepare salts with the labile tris(trimethylsilyl)chalconium ions, [(Me(3)Si)(3)E](+) (E=O, S), by reacting [Me(3)Si‐H‐SiMe(3)][B(C(6)F(5))(4)] and Me(3)Si[CB] (CB(−)=carborate=[CHB(11)H(5)Cl(6)](−), [CHB(11)Cl(11)](−)) with Me(3)Si‐E‐SiMe(3). In the reaction of Me(3)Si‐O‐...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028070/ https://www.ncbi.nlm.nih.gov/pubmed/31738450 http://dx.doi.org/10.1002/chem.201904403 |