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Cycloaddition Chemistry of a Silylene‐Nickel Complex toward Organic π‐Systems: From Reversibility to C−H Activation

The versatile cycloaddition chemistry of the Si−Ni multiple bond in the acyclic (amido)(chloro)silylene→Ni(0) complex 1, [((TMS)L)ClSi→Ni(NHC)(2)] ((TMS)L=N(SiMe(3))Dipp; Dipp=2,6‐iPr(2)C(6)H(4); NHC=C[(iPr)NC(Me)](2)), toward unsaturated organic substrates is reported, which is both reminiscent of...

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Detalles Bibliográficos
Autores principales:	Hadlington, Terrance J., Kostenko, Arseni, Driess, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028101/ https://www.ncbi.nlm.nih.gov/pubmed/31898825 http://dx.doi.org/10.1002/chem.202000009

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