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Three-Dimensional CuO/TiO(2) Hybrid Nanorod Arrays Prepared by Electrodeposition in AAO Membranes as an Excellent Fenton-Like Photocatalyst for Dye Degradation
Three-dimensional (3D) CuO/TiO(2) hybrid heterostructure nanorod arrays (NRs) with noble-metal-free composition, fabricated by template-assisted low-cost processes, were used as the photo-Fenton-like catalyst for dye degradation. Here, CuO NRs were deposited into anodic aluminum oxide templates by e...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Springer US
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028878/ https://www.ncbi.nlm.nih.gov/pubmed/32072311 http://dx.doi.org/10.1186/s11671-020-3266-6 |
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author | Date, Manisha Kondiba Yang, Li-Heng Yang, Tzu-Yi Wang, Kuang-ye Su, Teng-Yu Wu, Ding-Chou Cheuh, Yu-Lun |
author_facet | Date, Manisha Kondiba Yang, Li-Heng Yang, Tzu-Yi Wang, Kuang-ye Su, Teng-Yu Wu, Ding-Chou Cheuh, Yu-Lun |
author_sort | Date, Manisha Kondiba |
collection | PubMed |
description | Three-dimensional (3D) CuO/TiO(2) hybrid heterostructure nanorod arrays (NRs) with noble-metal-free composition, fabricated by template-assisted low-cost processes, were used as the photo-Fenton-like catalyst for dye degradation. Here, CuO NRs were deposited into anodic aluminum oxide templates by electrodeposition method annealed at various temperatures, followed by deposition of TiO(2) thin films through E-gun evaporation, resulting in the formation of CuO/TiO(2) p-n heterojunction. The distribution of elements and compositions of the CuO/TiO(2) p-n heterojunction were analyzed by EDS mapping and EELS profiles, respectively. In the presence of H(2)O(2), CuO/TiO(2) hybrid structure performed more efficiently than CuO NRs for Rhodamine B degradation under the irradiation of 500-W mercury-xenon arc lamp. This study demonstrated the effect of length of CuO NRs, on the photo-degradation performance of CuO NRs as well as CuO/TiO(2) heterostructure. The optimized CuO/TiO(2) hybrid NR array structure exhibited the highest photo-degradation activity, and the mechanism and role of photo-Fenton acting as the catalyst in photo-degradation of dye was also investigated. |
format | Online Article Text |
id | pubmed-7028878 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | Springer US |
record_format | MEDLINE/PubMed |
spelling | pubmed-70288782020-03-05 Three-Dimensional CuO/TiO(2) Hybrid Nanorod Arrays Prepared by Electrodeposition in AAO Membranes as an Excellent Fenton-Like Photocatalyst for Dye Degradation Date, Manisha Kondiba Yang, Li-Heng Yang, Tzu-Yi Wang, Kuang-ye Su, Teng-Yu Wu, Ding-Chou Cheuh, Yu-Lun Nanoscale Res Lett Nano Express Three-dimensional (3D) CuO/TiO(2) hybrid heterostructure nanorod arrays (NRs) with noble-metal-free composition, fabricated by template-assisted low-cost processes, were used as the photo-Fenton-like catalyst for dye degradation. Here, CuO NRs were deposited into anodic aluminum oxide templates by electrodeposition method annealed at various temperatures, followed by deposition of TiO(2) thin films through E-gun evaporation, resulting in the formation of CuO/TiO(2) p-n heterojunction. The distribution of elements and compositions of the CuO/TiO(2) p-n heterojunction were analyzed by EDS mapping and EELS profiles, respectively. In the presence of H(2)O(2), CuO/TiO(2) hybrid structure performed more efficiently than CuO NRs for Rhodamine B degradation under the irradiation of 500-W mercury-xenon arc lamp. This study demonstrated the effect of length of CuO NRs, on the photo-degradation performance of CuO NRs as well as CuO/TiO(2) heterostructure. The optimized CuO/TiO(2) hybrid NR array structure exhibited the highest photo-degradation activity, and the mechanism and role of photo-Fenton acting as the catalyst in photo-degradation of dye was also investigated. Springer US 2020-02-18 /pmc/articles/PMC7028878/ /pubmed/32072311 http://dx.doi.org/10.1186/s11671-020-3266-6 Text en © The Author(s). 2020 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. |
spellingShingle | Nano Express Date, Manisha Kondiba Yang, Li-Heng Yang, Tzu-Yi Wang, Kuang-ye Su, Teng-Yu Wu, Ding-Chou Cheuh, Yu-Lun Three-Dimensional CuO/TiO(2) Hybrid Nanorod Arrays Prepared by Electrodeposition in AAO Membranes as an Excellent Fenton-Like Photocatalyst for Dye Degradation |
title | Three-Dimensional CuO/TiO(2) Hybrid Nanorod Arrays Prepared by Electrodeposition in AAO Membranes as an Excellent Fenton-Like Photocatalyst for Dye Degradation |
title_full | Three-Dimensional CuO/TiO(2) Hybrid Nanorod Arrays Prepared by Electrodeposition in AAO Membranes as an Excellent Fenton-Like Photocatalyst for Dye Degradation |
title_fullStr | Three-Dimensional CuO/TiO(2) Hybrid Nanorod Arrays Prepared by Electrodeposition in AAO Membranes as an Excellent Fenton-Like Photocatalyst for Dye Degradation |
title_full_unstemmed | Three-Dimensional CuO/TiO(2) Hybrid Nanorod Arrays Prepared by Electrodeposition in AAO Membranes as an Excellent Fenton-Like Photocatalyst for Dye Degradation |
title_short | Three-Dimensional CuO/TiO(2) Hybrid Nanorod Arrays Prepared by Electrodeposition in AAO Membranes as an Excellent Fenton-Like Photocatalyst for Dye Degradation |
title_sort | three-dimensional cuo/tio(2) hybrid nanorod arrays prepared by electrodeposition in aao membranes as an excellent fenton-like photocatalyst for dye degradation |
topic | Nano Express |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028878/ https://www.ncbi.nlm.nih.gov/pubmed/32072311 http://dx.doi.org/10.1186/s11671-020-3266-6 |
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