Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide

[Image: see text] Titanium silicate molecular sieve (TS-1) and acetic acid efficiently catalyze the oxidation of furan and furan derivatives to the corresponding maleic acid (MA) in very good yields using hydrogen peroxide as an oxidizing agent. The effect of various solvents, the effect of temperat...

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Autores principales: Lou, Yuzhen, Marinkovic, Sinisa, Estrine, Boris, Qiang, Wei, Enderlin, Gérald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7033676/
https://www.ncbi.nlm.nih.gov/pubmed/32095680
http://dx.doi.org/10.1021/acsomega.9b02141
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author Lou, Yuzhen
Marinkovic, Sinisa
Estrine, Boris
Qiang, Wei
Enderlin, Gérald
author_facet Lou, Yuzhen
Marinkovic, Sinisa
Estrine, Boris
Qiang, Wei
Enderlin, Gérald
author_sort Lou, Yuzhen
collection PubMed
description [Image: see text] Titanium silicate molecular sieve (TS-1) and acetic acid efficiently catalyze the oxidation of furan and furan derivatives to the corresponding maleic acid (MA) in very good yields using hydrogen peroxide as an oxidizing agent. The effect of various solvents, the effect of temperature, reaction time, concentration of hydrogen peroxide, and quantities of the catalyst on the MA yield was studied. With the best conditions, MA is the sole product obtained after a fast and simple purification by filtration and evaporation. Compared to the previously reported methods, this work is a good compromise between the different reaction parameters and offers a good alternative to the production of biosourced MA.
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spelling pubmed-70336762020-02-24 Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide Lou, Yuzhen Marinkovic, Sinisa Estrine, Boris Qiang, Wei Enderlin, Gérald ACS Omega [Image: see text] Titanium silicate molecular sieve (TS-1) and acetic acid efficiently catalyze the oxidation of furan and furan derivatives to the corresponding maleic acid (MA) in very good yields using hydrogen peroxide as an oxidizing agent. The effect of various solvents, the effect of temperature, reaction time, concentration of hydrogen peroxide, and quantities of the catalyst on the MA yield was studied. With the best conditions, MA is the sole product obtained after a fast and simple purification by filtration and evaporation. Compared to the previously reported methods, this work is a good compromise between the different reaction parameters and offers a good alternative to the production of biosourced MA. American Chemical Society 2020-02-10 /pmc/articles/PMC7033676/ /pubmed/32095680 http://dx.doi.org/10.1021/acsomega.9b02141 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Lou, Yuzhen
Marinkovic, Sinisa
Estrine, Boris
Qiang, Wei
Enderlin, Gérald
Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide
title Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide
title_full Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide
title_fullStr Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide
title_full_unstemmed Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide
title_short Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide
title_sort oxidation of furfural and furan derivatives to maleic acid in the presence of a simple catalyst system based on acetic acid and ts-1 and hydrogen peroxide
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7033676/
https://www.ncbi.nlm.nih.gov/pubmed/32095680
http://dx.doi.org/10.1021/acsomega.9b02141
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