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Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation
The propargylation of aldehydes promoted by microwave irradiation using allenylboron compounds in a chemo- and regioselective way is described. The corresponding products were obtained in short reaction time, high yield and purity without the need of any solvent when allenylboronic acid pinacol este...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7034246/ https://www.ncbi.nlm.nih.gov/pubmed/32117473 http://dx.doi.org/10.3762/bjoc.16.19 |
| _version_ | 1783499839951077376 |
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| author | Freitas, Jucleiton J R Freitas, Queila P S B Andrade, Silvia R C P Freitas, Juliano C R Oliveira, Roberta A Menezes, Paulo H |
| author_facet | Freitas, Jucleiton J R Freitas, Queila P S B Andrade, Silvia R C P Freitas, Juliano C R Oliveira, Roberta A Menezes, Paulo H |
| author_sort | Freitas, Jucleiton J R |
| collection | PubMed |
| description | The propargylation of aldehydes promoted by microwave irradiation using allenylboron compounds in a chemo- and regioselective way is described. The corresponding products were obtained in short reaction time, high yield and purity without the need of any solvent when allenylboronic acid pinacol ester was used, or using a minimal amount of acetone when potassium allenyltrifluoroborate was used. |
| format | Online Article Text |
| id | pubmed-7034246 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-70342462020-02-28 Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation Freitas, Jucleiton J R Freitas, Queila P S B Andrade, Silvia R C P Freitas, Juliano C R Oliveira, Roberta A Menezes, Paulo H Beilstein J Org Chem Full Research Paper The propargylation of aldehydes promoted by microwave irradiation using allenylboron compounds in a chemo- and regioselective way is described. The corresponding products were obtained in short reaction time, high yield and purity without the need of any solvent when allenylboronic acid pinacol ester was used, or using a minimal amount of acetone when potassium allenyltrifluoroborate was used. Beilstein-Institut 2020-02-04 /pmc/articles/PMC7034246/ /pubmed/32117473 http://dx.doi.org/10.3762/bjoc.16.19 Text en Copyright © 2020, Freitas et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Freitas, Jucleiton J R Freitas, Queila P S B Andrade, Silvia R C P Freitas, Juliano C R Oliveira, Roberta A Menezes, Paulo H Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation |
| title | Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation |
| title_full | Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation |
| title_fullStr | Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation |
| title_full_unstemmed | Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation |
| title_short | Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation |
| title_sort | efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7034246/ https://www.ncbi.nlm.nih.gov/pubmed/32117473 http://dx.doi.org/10.3762/bjoc.16.19 |
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