Iron-Catalyzed Cross-Coupling of Bis-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and Mechanistic Investigations

Various substituted bis-(aryl)manganese species were prepared from aryl bromides by one-pot insertion of magnesium turnings in the presence of LiCl and in situ trans-metalation with MnCl(2) in THF at −5 °C within 2 h. These bis-(aryl)manganese reagents undergo smooth iron-catalyzed cross-couplings u...

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Detalles Bibliográficos
Autores principales: Rousseau, Lidie, Desaintjean, Alexandre, Knochel, Paul, Lefèvre, Guillaume
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037184/
https://www.ncbi.nlm.nih.gov/pubmed/32046047
http://dx.doi.org/10.3390/molecules25030723

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037184/
https://www.ncbi.nlm.nih.gov/pubmed/32046047
http://dx.doi.org/10.3390/molecules25030723

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