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1,2- and 1,1-Migratory Insertion Reactions of Silylated Germylene Adducts
The reactions of the PMe(3) adduct of the silylated germylene [(Me(3)Si)(3)Si](2)Ge: with GeCl(2)·dioxane were found to yield 1,1-migratory insertion products of GeCl(2) into one or two Ge–Si bonds. In a related reaction, a germylene was inserted with tris(trimethylsilyl)silyl and vinyl substituents...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037258/ https://www.ncbi.nlm.nih.gov/pubmed/32041130 http://dx.doi.org/10.3390/molecules25030686 |