Cargando…
Competition between Intra and Intermolecular Triel Bonds. Complexes between Naphthalene Derivatives and Neutral or Anionic Lewis Bases
A TrF(2) group (Tr = B, Al, Ga, In, Tl) is placed on one of the α positions of naphthalene, and its ability to engage in a triel bond (TrB) with a weak (NCH) and strong (NC(−)) nucleophile is assessed by ab initio calculations. As a competitor, an NH(2) group is placed on the neighboring C(α), from...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037318/ https://www.ncbi.nlm.nih.gov/pubmed/32024163 http://dx.doi.org/10.3390/molecules25030635 |