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Competition between Intra and Intermolecular Triel Bonds. Complexes between Naphthalene Derivatives and Neutral or Anionic Lewis Bases
A TrF(2) group (Tr = B, Al, Ga, In, Tl) is placed on one of the α positions of naphthalene, and its ability to engage in a triel bond (TrB) with a weak (NCH) and strong (NC(−)) nucleophile is assessed by ab initio calculations. As a competitor, an NH(2) group is placed on the neighboring C(α), from...
Autores principales: | Zierkiewicz, Wiktor, Michalczyk, Mariusz, Scheiner, Steve |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037318/ https://www.ncbi.nlm.nih.gov/pubmed/32024163 http://dx.doi.org/10.3390/molecules25030635 |
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