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The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline

Polyaniline is one of the most well studied conducting polymers due to its advanced electrical, chemical, redox and morphological properties. The high conductivity of regular polyaniline, when partially oxidized and doped under acidic conditions, has been associated with the formation of unique elec...

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Detalles Bibliográficos
Autores principales: Zujovic, Zoran, Kilmartin, Paul A., Travas-Sejdic, Jadranka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037364/
https://www.ncbi.nlm.nih.gov/pubmed/31973166
http://dx.doi.org/10.3390/molecules25030444
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author Zujovic, Zoran
Kilmartin, Paul A.
Travas-Sejdic, Jadranka
author_facet Zujovic, Zoran
Kilmartin, Paul A.
Travas-Sejdic, Jadranka
author_sort Zujovic, Zoran
collection PubMed
description Polyaniline is one of the most well studied conducting polymers due to its advanced electrical, chemical, redox and morphological properties. The high conductivity of regular polyaniline, when partially oxidized and doped under acidic conditions, has been associated with the formation of unique electronic states known as polarons and bipolarons. Alternative aniline oxidation products and interesting nanotube and nanorod forms have been observed as the synthesis conditions are varied. Solid-state NMR has offered great opportunities for structural investigations and the determination of molecular dynamics in such a complex and diverse material. This review summarizes various applications of solid-state NMR techniques to polyaniline and its derivatives and the information that can be obtained by solid-state NMR.
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spelling pubmed-70373642020-03-11 The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline Zujovic, Zoran Kilmartin, Paul A. Travas-Sejdic, Jadranka Molecules Review Polyaniline is one of the most well studied conducting polymers due to its advanced electrical, chemical, redox and morphological properties. The high conductivity of regular polyaniline, when partially oxidized and doped under acidic conditions, has been associated with the formation of unique electronic states known as polarons and bipolarons. Alternative aniline oxidation products and interesting nanotube and nanorod forms have been observed as the synthesis conditions are varied. Solid-state NMR has offered great opportunities for structural investigations and the determination of molecular dynamics in such a complex and diverse material. This review summarizes various applications of solid-state NMR techniques to polyaniline and its derivatives and the information that can be obtained by solid-state NMR. MDPI 2020-01-21 /pmc/articles/PMC7037364/ /pubmed/31973166 http://dx.doi.org/10.3390/molecules25030444 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Zujovic, Zoran
Kilmartin, Paul A.
Travas-Sejdic, Jadranka
The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline
title The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline
title_full The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline
title_fullStr The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline
title_full_unstemmed The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline
title_short The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline
title_sort applications of solid-state nmr to conducting polymers. the special case on polyaniline
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037364/
https://www.ncbi.nlm.nih.gov/pubmed/31973166
http://dx.doi.org/10.3390/molecules25030444
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