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Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials
Siloxane-based materials have a wide range of applications. Cage-type oligosiloxanes have attracted significant attention as molecular building blocks to construct novel siloxane-based nanoporous materials with promising applications such as in catalysis and adsorption. This paper reviews recent pro...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7038179/ https://www.ncbi.nlm.nih.gov/pubmed/31991787 http://dx.doi.org/10.3390/molecules25030524 |
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author | Shimojima, Atsushi Kuroda, Kazuyuki |
author_facet | Shimojima, Atsushi Kuroda, Kazuyuki |
author_sort | Shimojima, Atsushi |
collection | PubMed |
description | Siloxane-based materials have a wide range of applications. Cage-type oligosiloxanes have attracted significant attention as molecular building blocks to construct novel siloxane-based nanoporous materials with promising applications such as in catalysis and adsorption. This paper reviews recent progress in the preparation of siloxane-based nanoporous materials using alkoxy- and silanol-functionalized cage siloxanes. The arrangement of cage siloxanes units is controlled by various methods, including amphiphilic self-assembly, hydrogen bonding of silanol groups, and regioselective functionalization, toward the preparation of ordered nanoporous siloxane-based materials. |
format | Online Article Text |
id | pubmed-7038179 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-70381792020-03-10 Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials Shimojima, Atsushi Kuroda, Kazuyuki Molecules Review Siloxane-based materials have a wide range of applications. Cage-type oligosiloxanes have attracted significant attention as molecular building blocks to construct novel siloxane-based nanoporous materials with promising applications such as in catalysis and adsorption. This paper reviews recent progress in the preparation of siloxane-based nanoporous materials using alkoxy- and silanol-functionalized cage siloxanes. The arrangement of cage siloxanes units is controlled by various methods, including amphiphilic self-assembly, hydrogen bonding of silanol groups, and regioselective functionalization, toward the preparation of ordered nanoporous siloxane-based materials. MDPI 2020-01-25 /pmc/articles/PMC7038179/ /pubmed/31991787 http://dx.doi.org/10.3390/molecules25030524 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Shimojima, Atsushi Kuroda, Kazuyuki Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials |
title | Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials |
title_full | Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials |
title_fullStr | Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials |
title_full_unstemmed | Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials |
title_short | Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials |
title_sort | alkoxy- and silanol-functionalized cage-type oligosiloxanes as molecular building blocks to construct nanoporous materials |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7038179/ https://www.ncbi.nlm.nih.gov/pubmed/31991787 http://dx.doi.org/10.3390/molecules25030524 |
work_keys_str_mv | AT shimojimaatsushi alkoxyandsilanolfunctionalizedcagetypeoligosiloxanesasmolecularbuildingblockstoconstructnanoporousmaterials AT kurodakazuyuki alkoxyandsilanolfunctionalizedcagetypeoligosiloxanesasmolecularbuildingblockstoconstructnanoporousmaterials |