Cargando…

Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties †

The recycled polypropylene (rPP) materials that meet technical requirements such as reducing the dimensions and improving the tensile, elongation, impact strength, thermal stability, as well as melt processing, are required for the manufacturing industry. In this paper, we studied the mechanical and...

Descripción completa

Detalles Bibliográficos
Autores principales: Râpă, Maria, Spurcaciu, Bogdan Norocel, Coman, George, Nicolae, Cristian Andi, Gabor, Raluca Augusta, Ghioca, Paul Niculae, Berbecaru, Andrei Constantin, Matei, Ecaterina, Predescu, Cristian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7040787/
https://www.ncbi.nlm.nih.gov/pubmed/31979228
http://dx.doi.org/10.3390/ma13030543
_version_ 1783501062374686720
author Râpă, Maria
Spurcaciu, Bogdan Norocel
Coman, George
Nicolae, Cristian Andi
Gabor, Raluca Augusta
Ghioca, Paul Niculae
Berbecaru, Andrei Constantin
Matei, Ecaterina
Predescu, Cristian
author_facet Râpă, Maria
Spurcaciu, Bogdan Norocel
Coman, George
Nicolae, Cristian Andi
Gabor, Raluca Augusta
Ghioca, Paul Niculae
Berbecaru, Andrei Constantin
Matei, Ecaterina
Predescu, Cristian
author_sort Râpă, Maria
collection PubMed
description The recycled polypropylene (rPP) materials that meet technical requirements such as reducing the dimensions and improving the tensile, elongation, impact strength, thermal stability, as well as melt processing, are required for the manufacturing industry. In this paper, we studied the mechanical and thermal properties of post-consumer rPP by adding both synthesized thermoplastic elastomers, and glass bubbles (GB) by a melt allowing process. Styrene-butadiene (SBS) and styrene-isoprene (SIS) block-copolymers that had a styrene content of 30 wt% were synthesized by anionic sequential polymerization. The obtained post-consumer rPP composites were characterized by optical microscopy, scanning electron microscopy (SEM), mechanical analyses (tensile, density, hardness, VICAT softening temperature (VST), heat deflection temperature (HDT), dynamic mechanical analysis (DMA), IZOD strength) and thermal analyses (differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA)). Weight reduction and improvement of the tensile, elongation, impact strength, thermal stability, as well as melt processing of post-consumer recycled polypropylene (rPP) properties compounded with thermoplastic elastomers and glass bubbles, sustain the use of these formulations for engineering applications.
format Online
Article
Text
id pubmed-7040787
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-70407872020-03-09 Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties † Râpă, Maria Spurcaciu, Bogdan Norocel Coman, George Nicolae, Cristian Andi Gabor, Raluca Augusta Ghioca, Paul Niculae Berbecaru, Andrei Constantin Matei, Ecaterina Predescu, Cristian Materials (Basel) Article The recycled polypropylene (rPP) materials that meet technical requirements such as reducing the dimensions and improving the tensile, elongation, impact strength, thermal stability, as well as melt processing, are required for the manufacturing industry. In this paper, we studied the mechanical and thermal properties of post-consumer rPP by adding both synthesized thermoplastic elastomers, and glass bubbles (GB) by a melt allowing process. Styrene-butadiene (SBS) and styrene-isoprene (SIS) block-copolymers that had a styrene content of 30 wt% were synthesized by anionic sequential polymerization. The obtained post-consumer rPP composites were characterized by optical microscopy, scanning electron microscopy (SEM), mechanical analyses (tensile, density, hardness, VICAT softening temperature (VST), heat deflection temperature (HDT), dynamic mechanical analysis (DMA), IZOD strength) and thermal analyses (differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA)). Weight reduction and improvement of the tensile, elongation, impact strength, thermal stability, as well as melt processing of post-consumer recycled polypropylene (rPP) properties compounded with thermoplastic elastomers and glass bubbles, sustain the use of these formulations for engineering applications. MDPI 2020-01-23 /pmc/articles/PMC7040787/ /pubmed/31979228 http://dx.doi.org/10.3390/ma13030543 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Râpă, Maria
Spurcaciu, Bogdan Norocel
Coman, George
Nicolae, Cristian Andi
Gabor, Raluca Augusta
Ghioca, Paul Niculae
Berbecaru, Andrei Constantin
Matei, Ecaterina
Predescu, Cristian
Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties †
title Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties †
title_full Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties †
title_fullStr Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties †
title_full_unstemmed Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties †
title_short Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties †
title_sort effect of styrene-diene block copolymers and glass bubbles on the post-consumer recycled polypropylene properties †
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7040787/
https://www.ncbi.nlm.nih.gov/pubmed/31979228
http://dx.doi.org/10.3390/ma13030543
work_keys_str_mv AT rapamaria effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties
AT spurcaciubogdannorocel effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties
AT comangeorge effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties
AT nicolaecristianandi effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties
AT gaborralucaaugusta effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties
AT ghiocapaulniculae effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties
AT berbecaruandreiconstantin effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties
AT mateiecaterina effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties
AT predescucristian effectofstyrenedieneblockcopolymersandglassbubblesonthepostconsumerrecycledpolypropyleneproperties