Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide

[Image: see text] We prepared a series of ordered mesoporous carbons embedded with different contents of Cu nanoparticles (Cu/OMC-X) and applied them to electrocatalytic synthesis of benzyl methyl carbonate. The materials were characterized by many measurements, which showed that Cu/OMC-X materials...

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Autores principales: Hu, Qiao-Li, Zhang, Zhi-Xia, Zhang, Jing-Jie, Li, Shi-Ming, Wang, Huan, Lu, Jia-Xing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7045572/
https://www.ncbi.nlm.nih.gov/pubmed/32118164
http://dx.doi.org/10.1021/acsomega.9b03651
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author Hu, Qiao-Li
Zhang, Zhi-Xia
Zhang, Jing-Jie
Li, Shi-Ming
Wang, Huan
Lu, Jia-Xing
author_facet Hu, Qiao-Li
Zhang, Zhi-Xia
Zhang, Jing-Jie
Li, Shi-Ming
Wang, Huan
Lu, Jia-Xing
author_sort Hu, Qiao-Li
collection PubMed
description [Image: see text] We prepared a series of ordered mesoporous carbons embedded with different contents of Cu nanoparticles (Cu/OMC-X) and applied them to electrocatalytic synthesis of benzyl methyl carbonate. The materials were characterized by many measurements, which showed that Cu/OMC-X materials maintain highly ordered mesoporous structures with high surface area and highly dispersed Cu nanoparticles. As expected, the materials exhibit good electrocatalytic performance. The optimal yield of benzyl methyl carbonate reaches 69.7% on Cu/OMC-3.
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spelling pubmed-70455722020-02-28 Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide Hu, Qiao-Li Zhang, Zhi-Xia Zhang, Jing-Jie Li, Shi-Ming Wang, Huan Lu, Jia-Xing ACS Omega [Image: see text] We prepared a series of ordered mesoporous carbons embedded with different contents of Cu nanoparticles (Cu/OMC-X) and applied them to electrocatalytic synthesis of benzyl methyl carbonate. The materials were characterized by many measurements, which showed that Cu/OMC-X materials maintain highly ordered mesoporous structures with high surface area and highly dispersed Cu nanoparticles. As expected, the materials exhibit good electrocatalytic performance. The optimal yield of benzyl methyl carbonate reaches 69.7% on Cu/OMC-3. American Chemical Society 2020-02-14 /pmc/articles/PMC7045572/ /pubmed/32118164 http://dx.doi.org/10.1021/acsomega.9b03651 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Hu, Qiao-Li
Zhang, Zhi-Xia
Zhang, Jing-Jie
Li, Shi-Ming
Wang, Huan
Lu, Jia-Xing
Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide
title Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide
title_full Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide
title_fullStr Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide
title_full_unstemmed Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide
title_short Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide
title_sort ordered mesoporous carbon embedded with cu nanoparticle materials for electrocatalytic synthesis of benzyl methyl carbonate from benzyl alcohol and carbon dioxide
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7045572/
https://www.ncbi.nlm.nih.gov/pubmed/32118164
http://dx.doi.org/10.1021/acsomega.9b03651
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