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Molecular and Supramolecular Multiredox Systems
The design and synthesis of molecular and supramolecular multiredox systems have been summarized. These systems are of great importance as they can be employed in the next generation of materials for energy storage, energy transport, and solar fuel production. Nature provides guiding pathways and in...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7050954/ https://www.ncbi.nlm.nih.gov/pubmed/32154051 http://dx.doi.org/10.1002/open.201900339 |
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author | Shukla, Jyoti Singh, Vijay Pal Mukhopadhyay, Pritam |
author_facet | Shukla, Jyoti Singh, Vijay Pal Mukhopadhyay, Pritam |
author_sort | Shukla, Jyoti |
collection | PubMed |
description | The design and synthesis of molecular and supramolecular multiredox systems have been summarized. These systems are of great importance as they can be employed in the next generation of materials for energy storage, energy transport, and solar fuel production. Nature provides guiding pathways and insights to judiciously incorporate and tune the various molecular and supramolecular design aspects that result in the formation of complex and efficient systems. In this review, we have classified molecular multiredox systems into organic and organic‐inorganic hybrid systems. The organic multiredox systems are further classified into multielectron acceptors, multielectron donors and ambipolar molecules. Synthetic chemists have integrated different electron donating and electron withdrawing groups to realize these complex molecular systems. Further, we have reviewed supramolecular multiredox systems, redox‐active host‐guest recognition, including mechanically interlocked systems. Finally, the review provides a discussion on the diverse applications, e. g. in artificial photosynthesis, water splitting, dynamic random access memory, etc. that can be realized from these artificial molecular or supramolecular multiredox systems. |
format | Online Article Text |
id | pubmed-7050954 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-70509542020-03-09 Molecular and Supramolecular Multiredox Systems Shukla, Jyoti Singh, Vijay Pal Mukhopadhyay, Pritam ChemistryOpen Reviews The design and synthesis of molecular and supramolecular multiredox systems have been summarized. These systems are of great importance as they can be employed in the next generation of materials for energy storage, energy transport, and solar fuel production. Nature provides guiding pathways and insights to judiciously incorporate and tune the various molecular and supramolecular design aspects that result in the formation of complex and efficient systems. In this review, we have classified molecular multiredox systems into organic and organic‐inorganic hybrid systems. The organic multiredox systems are further classified into multielectron acceptors, multielectron donors and ambipolar molecules. Synthetic chemists have integrated different electron donating and electron withdrawing groups to realize these complex molecular systems. Further, we have reviewed supramolecular multiredox systems, redox‐active host‐guest recognition, including mechanically interlocked systems. Finally, the review provides a discussion on the diverse applications, e. g. in artificial photosynthesis, water splitting, dynamic random access memory, etc. that can be realized from these artificial molecular or supramolecular multiredox systems. John Wiley and Sons Inc. 2020-03-02 /pmc/articles/PMC7050954/ /pubmed/32154051 http://dx.doi.org/10.1002/open.201900339 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
spellingShingle | Reviews Shukla, Jyoti Singh, Vijay Pal Mukhopadhyay, Pritam Molecular and Supramolecular Multiredox Systems |
title | Molecular and Supramolecular Multiredox Systems |
title_full | Molecular and Supramolecular Multiredox Systems |
title_fullStr | Molecular and Supramolecular Multiredox Systems |
title_full_unstemmed | Molecular and Supramolecular Multiredox Systems |
title_short | Molecular and Supramolecular Multiredox Systems |
title_sort | molecular and supramolecular multiredox systems |
topic | Reviews |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7050954/ https://www.ncbi.nlm.nih.gov/pubmed/32154051 http://dx.doi.org/10.1002/open.201900339 |
work_keys_str_mv | AT shuklajyoti molecularandsupramolecularmultiredoxsystems AT singhvijaypal molecularandsupramolecularmultiredoxsystems AT mukhopadhyaypritam molecularandsupramolecularmultiredoxsystems |