Two-Dimensional Hydrogen-Bonded Nanoarchitecture Composed of Rectangular 3,4,9,10-Perylenetetracarboxylic Diimide and Boomerang-Shaped Molecules Resulting from the Dissociation of 1,3,5-Tris(4-aminophenyl)benzene

[Image: see text] The self-assembly of 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) with the star-shaped 1,3,5-tris(4-aminophenyl)benzene (TAPB) on Au(111) is investigated using scanning tunneling microscopy. PTCDI forms a compact canted arrangement on the gold surface. When TAPB is sublimated a...

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Autores principales: Hieulle, Jeremy, Silly, Fabien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7057330/
https://www.ncbi.nlm.nih.gov/pubmed/32149223
http://dx.doi.org/10.1021/acsomega.9b03453
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author Hieulle, Jeremy
Silly, Fabien
author_facet Hieulle, Jeremy
Silly, Fabien
author_sort Hieulle, Jeremy
collection PubMed
description [Image: see text] The self-assembly of 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) with the star-shaped 1,3,5-tris(4-aminophenyl)benzene (TAPB) on Au(111) is investigated using scanning tunneling microscopy. PTCDI forms a compact canted arrangement on the gold surface. When TAPB is sublimated at a high temperature, the molecule dissociates into a 4-aminophenyl group and a boomerang-shaped compound. The boomerang molecule self-assembles with PTCDI to create a two-dimensional (2D) nanoarchitecture stabilized by N–H···O–C hydrogen bonds between the dissociated TAPB and PTCDI. The molecular ratio of this multicomponent structure is 1:1.
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spelling pubmed-70573302020-03-06 Two-Dimensional Hydrogen-Bonded Nanoarchitecture Composed of Rectangular 3,4,9,10-Perylenetetracarboxylic Diimide and Boomerang-Shaped Molecules Resulting from the Dissociation of 1,3,5-Tris(4-aminophenyl)benzene Hieulle, Jeremy Silly, Fabien ACS Omega [Image: see text] The self-assembly of 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) with the star-shaped 1,3,5-tris(4-aminophenyl)benzene (TAPB) on Au(111) is investigated using scanning tunneling microscopy. PTCDI forms a compact canted arrangement on the gold surface. When TAPB is sublimated at a high temperature, the molecule dissociates into a 4-aminophenyl group and a boomerang-shaped compound. The boomerang molecule self-assembles with PTCDI to create a two-dimensional (2D) nanoarchitecture stabilized by N–H···O–C hydrogen bonds between the dissociated TAPB and PTCDI. The molecular ratio of this multicomponent structure is 1:1. American Chemical Society 2020-02-19 /pmc/articles/PMC7057330/ /pubmed/32149223 http://dx.doi.org/10.1021/acsomega.9b03453 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Hieulle, Jeremy
Silly, Fabien
Two-Dimensional Hydrogen-Bonded Nanoarchitecture Composed of Rectangular 3,4,9,10-Perylenetetracarboxylic Diimide and Boomerang-Shaped Molecules Resulting from the Dissociation of 1,3,5-Tris(4-aminophenyl)benzene
title Two-Dimensional Hydrogen-Bonded Nanoarchitecture Composed of Rectangular 3,4,9,10-Perylenetetracarboxylic Diimide and Boomerang-Shaped Molecules Resulting from the Dissociation of 1,3,5-Tris(4-aminophenyl)benzene
title_full Two-Dimensional Hydrogen-Bonded Nanoarchitecture Composed of Rectangular 3,4,9,10-Perylenetetracarboxylic Diimide and Boomerang-Shaped Molecules Resulting from the Dissociation of 1,3,5-Tris(4-aminophenyl)benzene
title_fullStr Two-Dimensional Hydrogen-Bonded Nanoarchitecture Composed of Rectangular 3,4,9,10-Perylenetetracarboxylic Diimide and Boomerang-Shaped Molecules Resulting from the Dissociation of 1,3,5-Tris(4-aminophenyl)benzene
title_full_unstemmed Two-Dimensional Hydrogen-Bonded Nanoarchitecture Composed of Rectangular 3,4,9,10-Perylenetetracarboxylic Diimide and Boomerang-Shaped Molecules Resulting from the Dissociation of 1,3,5-Tris(4-aminophenyl)benzene
title_short Two-Dimensional Hydrogen-Bonded Nanoarchitecture Composed of Rectangular 3,4,9,10-Perylenetetracarboxylic Diimide and Boomerang-Shaped Molecules Resulting from the Dissociation of 1,3,5-Tris(4-aminophenyl)benzene
title_sort two-dimensional hydrogen-bonded nanoarchitecture composed of rectangular 3,4,9,10-perylenetetracarboxylic diimide and boomerang-shaped molecules resulting from the dissociation of 1,3,5-tris(4-aminophenyl)benzene
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7057330/
https://www.ncbi.nlm.nih.gov/pubmed/32149223
http://dx.doi.org/10.1021/acsomega.9b03453
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AT sillyfabien twodimensionalhydrogenbondednanoarchitecturecomposedofrectangular34910perylenetetracarboxylicdiimideandboomerangshapedmoleculesresultingfromthedissociationof135tris4aminophenylbenzene

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