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Crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(II)

The unit cell of the title compound, [Zn(C(17)H(18)N(3)O(4))(2)]·CH(4)O·C(2)H(6)O, contains two complex mol­ecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimeth...

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Autores principales: Znovjyak, Kateryna, Fritsky, Igor O., Sliva, Tatiana Y., Amirkhanov, Vladimir M., Seredyuk, Maksym
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7057386/
https://www.ncbi.nlm.nih.gov/pubmed/32148865
http://dx.doi.org/10.1107/S2056989020000857
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author Znovjyak, Kateryna
Fritsky, Igor O.
Sliva, Tatiana Y.
Amirkhanov, Vladimir M.
Seredyuk, Maksym
author_facet Znovjyak, Kateryna
Fritsky, Igor O.
Sliva, Tatiana Y.
Amirkhanov, Vladimir M.
Seredyuk, Maksym
author_sort Znovjyak, Kateryna
collection PubMed
description The unit cell of the title compound, [Zn(C(17)H(18)N(3)O(4))(2)]·CH(4)O·C(2)H(6)O, contains two complex mol­ecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazide} coordinate to the Zn(II) ion through the N atoms of the pyridine group and the ketamine, and, additionally, through the O atom of the enolate group. In the crystal, dimers are formed by π–π inter­actions between the planar ligand moieties, which are further connected by C⋯O and C⋯C inter­actions. The inter­molecular inter­actions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most important contributions for the crystal packing are from H⋯H (44.8%), H⋯C/C⋯H (22.2%), H⋯O/O⋯H (18.7%) and C⋯C (3.9%) inter­actions.
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spelling pubmed-70573862020-03-06 Crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(II) Znovjyak, Kateryna Fritsky, Igor O. Sliva, Tatiana Y. Amirkhanov, Vladimir M. Seredyuk, Maksym Acta Crystallogr E Crystallogr Commun Research Communications The unit cell of the title compound, [Zn(C(17)H(18)N(3)O(4))(2)]·CH(4)O·C(2)H(6)O, contains two complex mol­ecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazide} coordinate to the Zn(II) ion through the N atoms of the pyridine group and the ketamine, and, additionally, through the O atom of the enolate group. In the crystal, dimers are formed by π–π inter­actions between the planar ligand moieties, which are further connected by C⋯O and C⋯C inter­actions. The inter­molecular inter­actions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most important contributions for the crystal packing are from H⋯H (44.8%), H⋯C/C⋯H (22.2%), H⋯O/O⋯H (18.7%) and C⋯C (3.9%) inter­actions. International Union of Crystallography 2020-02-06 /pmc/articles/PMC7057386/ /pubmed/32148865 http://dx.doi.org/10.1107/S2056989020000857 Text en © Znovjyak et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Znovjyak, Kateryna
Fritsky, Igor O.
Sliva, Tatiana Y.
Amirkhanov, Vladimir M.
Seredyuk, Maksym
Crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(II)
title Crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(II)
title_full Crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(II)
title_fullStr Crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(II)
title_full_unstemmed Crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(II)
title_short Crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-N′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(II)
title_sort crystal structure of the mixed methanol and ethanol solvate of bis­{3,4,5-trimeth­oxy-n′-[1-(pyridin-2-yl)ethyl­idene]benzohydrazidato}zinc(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7057386/
https://www.ncbi.nlm.nih.gov/pubmed/32148865
http://dx.doi.org/10.1107/S2056989020000857
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