Cargando…
Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II)
The unit cell of the title compound, [Zn(C(17)H(18)N(3)O(4))(2)]·CH(4)O·C(2)H(6)O, contains two complex molecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimeth...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7057386/ https://www.ncbi.nlm.nih.gov/pubmed/32148865 http://dx.doi.org/10.1107/S2056989020000857 |
_version_ | 1783503644998500352 |
---|---|
author | Znovjyak, Kateryna Fritsky, Igor O. Sliva, Tatiana Y. Amirkhanov, Vladimir M. Seredyuk, Maksym |
author_facet | Znovjyak, Kateryna Fritsky, Igor O. Sliva, Tatiana Y. Amirkhanov, Vladimir M. Seredyuk, Maksym |
author_sort | Znovjyak, Kateryna |
collection | PubMed |
description | The unit cell of the title compound, [Zn(C(17)H(18)N(3)O(4))(2)]·CH(4)O·C(2)H(6)O, contains two complex molecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazide} coordinate to the Zn(II) ion through the N atoms of the pyridine group and the ketamine, and, additionally, through the O atom of the enolate group. In the crystal, dimers are formed by π–π interactions between the planar ligand moieties, which are further connected by C⋯O and C⋯C interactions. The intermolecular interactions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most important contributions for the crystal packing are from H⋯H (44.8%), H⋯C/C⋯H (22.2%), H⋯O/O⋯H (18.7%) and C⋯C (3.9%) interactions. |
format | Online Article Text |
id | pubmed-7057386 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-70573862020-03-06 Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II) Znovjyak, Kateryna Fritsky, Igor O. Sliva, Tatiana Y. Amirkhanov, Vladimir M. Seredyuk, Maksym Acta Crystallogr E Crystallogr Commun Research Communications The unit cell of the title compound, [Zn(C(17)H(18)N(3)O(4))(2)]·CH(4)O·C(2)H(6)O, contains two complex molecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazide} coordinate to the Zn(II) ion through the N atoms of the pyridine group and the ketamine, and, additionally, through the O atom of the enolate group. In the crystal, dimers are formed by π–π interactions between the planar ligand moieties, which are further connected by C⋯O and C⋯C interactions. The intermolecular interactions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most important contributions for the crystal packing are from H⋯H (44.8%), H⋯C/C⋯H (22.2%), H⋯O/O⋯H (18.7%) and C⋯C (3.9%) interactions. International Union of Crystallography 2020-02-06 /pmc/articles/PMC7057386/ /pubmed/32148865 http://dx.doi.org/10.1107/S2056989020000857 Text en © Znovjyak et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Znovjyak, Kateryna Fritsky, Igor O. Sliva, Tatiana Y. Amirkhanov, Vladimir M. Seredyuk, Maksym Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II) |
title | Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II) |
title_full | Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II) |
title_fullStr | Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II) |
title_full_unstemmed | Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II) |
title_short | Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II) |
title_sort | crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-n′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7057386/ https://www.ncbi.nlm.nih.gov/pubmed/32148865 http://dx.doi.org/10.1107/S2056989020000857 |
work_keys_str_mv | AT znovjyakkateryna crystalstructureofthemixedmethanolandethanolsolvateofbis345trimethoxyn1pyridin2ylethylidenebenzohydrazidatozincii AT fritskyigoro crystalstructureofthemixedmethanolandethanolsolvateofbis345trimethoxyn1pyridin2ylethylidenebenzohydrazidatozincii AT slivatatianay crystalstructureofthemixedmethanolandethanolsolvateofbis345trimethoxyn1pyridin2ylethylidenebenzohydrazidatozincii AT amirkhanovvladimirm crystalstructureofthemixedmethanolandethanolsolvateofbis345trimethoxyn1pyridin2ylethylidenebenzohydrazidatozincii AT seredyukmaksym crystalstructureofthemixedmethanolandethanolsolvateofbis345trimethoxyn1pyridin2ylethylidenebenzohydrazidatozincii |