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Soft interactions with hard Lewis acids: generation of mono- and dicationic alkaline-earth metal arene-complexes by direct oxidation
The synthesis of the first unsupported dicationic arene complexes of calcium and strontium [(η(6)-HMB)AE(oDFB)(4)](2+) is reported (HMB = hexamethylbenzene; AE = alkaline earth metal; oDFB = ortho-difluorobenzene). They were prepared by direct oxidation of the elemental metals employing the ligand-f...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7057851/ https://www.ncbi.nlm.nih.gov/pubmed/32180929 http://dx.doi.org/10.1039/c9sc06254h |