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A Covalent and Modular Synthesis of Homo- and Hetero[n]rotaxanes
[Image: see text] Incorporation of 2,5-dihydroxyterephthalate as a covalent scaffold in the axis of a 30-membered all-carbon macrocycle provides access to a modular series of rotaxanes. Installment of tethered alkynes or azides onto the terephthalic phenolic hydroxyl functionalities, which are situa...
Autores principales: | Cornelissen, Milo D., Pilon, Simone, Steemers, Luuk, Wanner, Martin J., Frölke, Steven, Zuidinga, Ed, Jørgensen, Steen Ingemann, van der Vlugt, Jarl Ivar, van Maarseveen, Jan H. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7063575/ https://www.ncbi.nlm.nih.gov/pubmed/31965801 http://dx.doi.org/10.1021/acs.joc.9b03030 |
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