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Titanium‐Catalyzed Hydroaminoalkylation of Ethylene
The first examples of titanium‐catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid‐state structure of a titanap...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7064915/ https://www.ncbi.nlm.nih.gov/pubmed/31799706 http://dx.doi.org/10.1002/chem.201904502 |
| Sumario: | The first examples of titanium‐catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid‐state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti−C bond of a titanaaziridine is reported. |
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