Titanium‐Catalyzed Hydroaminoalkylation of Ethylene

The first examples of titanium‐catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid‐state structure of a titanap...

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Detalles Bibliográficos
Autores principales: Rosien, Michael, Töben, Iris, Schmidtmann, Marc, Beckhaus, Rüdiger, Doye, Sven
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7064915/
https://www.ncbi.nlm.nih.gov/pubmed/31799706
http://dx.doi.org/10.1002/chem.201904502
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author Rosien, Michael
Töben, Iris
Schmidtmann, Marc
Beckhaus, Rüdiger
Doye, Sven
author_facet Rosien, Michael
Töben, Iris
Schmidtmann, Marc
Beckhaus, Rüdiger
Doye, Sven
author_sort Rosien, Michael
collection PubMed
description The first examples of titanium‐catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid‐state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti−C bond of a titanaaziridine is reported.
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spelling pubmed-70649152020-03-16 Titanium‐Catalyzed Hydroaminoalkylation of Ethylene Rosien, Michael Töben, Iris Schmidtmann, Marc Beckhaus, Rüdiger Doye, Sven Chemistry Communications The first examples of titanium‐catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid‐state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti−C bond of a titanaaziridine is reported. John Wiley and Sons Inc. 2020-01-20 2020-02-17 /pmc/articles/PMC7064915/ /pubmed/31799706 http://dx.doi.org/10.1002/chem.201904502 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Rosien, Michael
Töben, Iris
Schmidtmann, Marc
Beckhaus, Rüdiger
Doye, Sven
Titanium‐Catalyzed Hydroaminoalkylation of Ethylene
title Titanium‐Catalyzed Hydroaminoalkylation of Ethylene
title_full Titanium‐Catalyzed Hydroaminoalkylation of Ethylene
title_fullStr Titanium‐Catalyzed Hydroaminoalkylation of Ethylene
title_full_unstemmed Titanium‐Catalyzed Hydroaminoalkylation of Ethylene
title_short Titanium‐Catalyzed Hydroaminoalkylation of Ethylene
title_sort titanium‐catalyzed hydroaminoalkylation of ethylene
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7064915/
https://www.ncbi.nlm.nih.gov/pubmed/31799706
http://dx.doi.org/10.1002/chem.201904502
work_keys_str_mv AT rosienmichael titaniumcatalyzedhydroaminoalkylationofethylene
AT tobeniris titaniumcatalyzedhydroaminoalkylationofethylene
AT schmidtmannmarc titaniumcatalyzedhydroaminoalkylationofethylene
AT beckhausrudiger titaniumcatalyzedhydroaminoalkylationofethylene
AT doyesven titaniumcatalyzedhydroaminoalkylationofethylene

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