Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant

A mild procedure for the oxidative C−C cross‐coupling of tertiary anilines with phenols is described which provides the products generally in high yields and with excellent selectivity. The reaction is catalyzed by the hexadecafluorinated iron–phthalocyanine complex FePcF(16) in the presence of subs...

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Detalles Bibliográficos
Autores principales: Purtsas, Alexander, Kataeva, Olga, Knölker, Hans‐Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
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Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7064917/
https://www.ncbi.nlm.nih.gov/pubmed/31858652
http://dx.doi.org/10.1002/chem.201905595
Descripción
Sumario:A mild procedure for the oxidative C−C cross‐coupling of tertiary anilines with phenols is described which provides the products generally in high yields and with excellent selectivity. The reaction is catalyzed by the hexadecafluorinated iron–phthalocyanine complex FePcF(16) in the presence of substoichiometric amounts of methanesulfonic acid and ambient air as sole oxidant.

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