Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant

A mild procedure for the oxidative C−C cross‐coupling of tertiary anilines with phenols is described which provides the products generally in high yields and with excellent selectivity. The reaction is catalyzed by the hexadecafluorinated iron–phthalocyanine complex FePcF(16) in the presence of subs...

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Autores principales: Purtsas, Alexander, Kataeva, Olga, Knölker, Hans‐Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7064917/
https://www.ncbi.nlm.nih.gov/pubmed/31858652
http://dx.doi.org/10.1002/chem.201905595
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author Purtsas, Alexander
Kataeva, Olga
Knölker, Hans‐Joachim
author_facet Purtsas, Alexander
Kataeva, Olga
Knölker, Hans‐Joachim
author_sort Purtsas, Alexander
collection PubMed
description A mild procedure for the oxidative C−C cross‐coupling of tertiary anilines with phenols is described which provides the products generally in high yields and with excellent selectivity. The reaction is catalyzed by the hexadecafluorinated iron–phthalocyanine complex FePcF(16) in the presence of substoichiometric amounts of methanesulfonic acid and ambient air as sole oxidant.
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spelling pubmed-70649172020-03-16 Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant Purtsas, Alexander Kataeva, Olga Knölker, Hans‐Joachim Chemistry Full Papers A mild procedure for the oxidative C−C cross‐coupling of tertiary anilines with phenols is described which provides the products generally in high yields and with excellent selectivity. The reaction is catalyzed by the hexadecafluorinated iron–phthalocyanine complex FePcF(16) in the presence of substoichiometric amounts of methanesulfonic acid and ambient air as sole oxidant. John Wiley and Sons Inc. 2020-02-04 2020-02-21 /pmc/articles/PMC7064917/ /pubmed/31858652 http://dx.doi.org/10.1002/chem.201905595 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Purtsas, Alexander
Kataeva, Olga
Knölker, Hans‐Joachim
Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant
title Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant
title_full Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant
title_fullStr Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant
title_full_unstemmed Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant
title_short Iron‐Catalyzed Oxidative C−C Cross‐Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant
title_sort iron‐catalyzed oxidative c−c cross‐coupling reaction of tertiary anilines with hydroxyarenes by using air as sole oxidant
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7064917/
https://www.ncbi.nlm.nih.gov/pubmed/31858652
http://dx.doi.org/10.1002/chem.201905595
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AT knolkerhansjoachim ironcatalyzedoxidativecccrosscouplingreactionoftertiaryanilineswithhydroxyarenesbyusingairassoleoxidant

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