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Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO)(6)
Esters and amides were mechanochemically prepared by palladium‐catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real‐time monitoring of the mechanochemical reaction by i...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7065133/ https://www.ncbi.nlm.nih.gov/pubmed/31802549 http://dx.doi.org/10.1002/chem.201904528 |
| _version_ | 1783505005175635968 |
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| author | van Bonn, Pit Bolm, Carsten Hernández, José G. |
| author_facet | van Bonn, Pit Bolm, Carsten Hernández, José G. |
| author_sort | van Bonn, Pit |
| collection | PubMed |
| description | Esters and amides were mechanochemically prepared by palladium‐catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real‐time monitoring of the mechanochemical reaction by in situ pressure sensing revealed that CO is rapidly transferred from Mo(CO)(6) to the active catalytic system without significant release of molecular carbon monoxide. |
| format | Online Article Text |
| id | pubmed-7065133 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-70651332020-03-16 Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO)(6) van Bonn, Pit Bolm, Carsten Hernández, José G. Chemistry Communications Esters and amides were mechanochemically prepared by palladium‐catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real‐time monitoring of the mechanochemical reaction by in situ pressure sensing revealed that CO is rapidly transferred from Mo(CO)(6) to the active catalytic system without significant release of molecular carbon monoxide. John Wiley and Sons Inc. 2020-02-11 2020-02-26 /pmc/articles/PMC7065133/ /pubmed/31802549 http://dx.doi.org/10.1002/chem.201904528 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
| spellingShingle | Communications van Bonn, Pit Bolm, Carsten Hernández, José G. Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO)(6) |
| title | Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO)(6)
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| title_full | Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO)(6)
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| title_fullStr | Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO)(6)
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| title_full_unstemmed | Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO)(6)
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| title_short | Mechanochemical Palladium‐Catalyzed Carbonylative Reactions Using Mo(CO)(6)
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| title_sort | mechanochemical palladium‐catalyzed carbonylative reactions using mo(co)(6) |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7065133/ https://www.ncbi.nlm.nih.gov/pubmed/31802549 http://dx.doi.org/10.1002/chem.201904528 |
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