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Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride

In this work, the highly efficient and low-cost Ag-AgBr/AlOOH plasmonic photocatalyst is successfully prepared via a simple and mild wet-chemical process and used for degrading high concentration methylene blue (MB) and tetracycline hydrochloride (TCH). The optimized 6-Ag-AgBr/AlOOH sample showed a...

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Autores principales: Zhang, Siyang, Khan, Iltaf, Qin, Xiaohong, Qi, Kezhen, Liu, Ying, Bai, Shuchong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7066255/
https://www.ncbi.nlm.nih.gov/pubmed/32195222
http://dx.doi.org/10.3389/fchem.2020.00117
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author Zhang, Siyang
Khan, Iltaf
Qin, Xiaohong
Qi, Kezhen
Liu, Ying
Bai, Shuchong
author_facet Zhang, Siyang
Khan, Iltaf
Qin, Xiaohong
Qi, Kezhen
Liu, Ying
Bai, Shuchong
author_sort Zhang, Siyang
collection PubMed
description In this work, the highly efficient and low-cost Ag-AgBr/AlOOH plasmonic photocatalyst is successfully prepared via a simple and mild wet-chemical process and used for degrading high concentration methylene blue (MB) and tetracycline hydrochloride (TCH). The optimized 6-Ag-AgBr/AlOOH sample showed a 79% decomposition of TCH in 2 h, which is almost two times higher than that of bare AgBr (37%). For degrading MB, the photocatalytic activity of 6-Ag-AgBr/AlOOH (decomposing 84% in 2 h) showed a large enhancement as compared to bare AgBr (only 57%). The TEM, HRTEM, XRD, DRS, and XPS characterization results confirm that Ag-AgBr is a composite catalyst formed by loading Ag nanoparticles onto AgBr surfaces and then loaded on to AlOOH. The possible mechanism proposed is that • [Formula: see text] and •OH radicals produced under sun light are the main active species for degrading MB and TCH. It is hoped that this work will open a new gateway to the synthesis of highly efficient and low-cost Ag-AgBr/AlOOH plasmonic photocatalysts for degrading organic pollutants.
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spelling pubmed-70662552020-03-19 Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride Zhang, Siyang Khan, Iltaf Qin, Xiaohong Qi, Kezhen Liu, Ying Bai, Shuchong Front Chem Chemistry In this work, the highly efficient and low-cost Ag-AgBr/AlOOH plasmonic photocatalyst is successfully prepared via a simple and mild wet-chemical process and used for degrading high concentration methylene blue (MB) and tetracycline hydrochloride (TCH). The optimized 6-Ag-AgBr/AlOOH sample showed a 79% decomposition of TCH in 2 h, which is almost two times higher than that of bare AgBr (37%). For degrading MB, the photocatalytic activity of 6-Ag-AgBr/AlOOH (decomposing 84% in 2 h) showed a large enhancement as compared to bare AgBr (only 57%). The TEM, HRTEM, XRD, DRS, and XPS characterization results confirm that Ag-AgBr is a composite catalyst formed by loading Ag nanoparticles onto AgBr surfaces and then loaded on to AlOOH. The possible mechanism proposed is that • [Formula: see text] and •OH radicals produced under sun light are the main active species for degrading MB and TCH. It is hoped that this work will open a new gateway to the synthesis of highly efficient and low-cost Ag-AgBr/AlOOH plasmonic photocatalysts for degrading organic pollutants. Frontiers Media S.A. 2020-03-05 /pmc/articles/PMC7066255/ /pubmed/32195222 http://dx.doi.org/10.3389/fchem.2020.00117 Text en Copyright © 2020 Zhang, Khan, Qin, Qi, Liu and Bai. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Zhang, Siyang
Khan, Iltaf
Qin, Xiaohong
Qi, Kezhen
Liu, Ying
Bai, Shuchong
Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride
title Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride
title_full Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride
title_fullStr Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride
title_full_unstemmed Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride
title_short Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride
title_sort construction of 1d ag-agbr/alooh plasmonic photocatalyst for degradation of tetracycline hydrochloride
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7066255/
https://www.ncbi.nlm.nih.gov/pubmed/32195222
http://dx.doi.org/10.3389/fchem.2020.00117
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