Cargando…
Trapping an unprecedented Ti(3)C(3) unit inside the icosahedral C(80) fullerene: a crystallographic survey
The sub-nanometer cavity of fullerene cages is an ideal platform to accommodate otherwise unstable species for accurate structural characterization with, for example, rather accurate single crystal X-ray diffraction (XRD) crystallography. Herein, we report the successful entrapment of an isolated Ti...
Autores principales: | Yu, Pengyuan, Shen, Wangqiang, Bao, Lipiao, Pan, Changwang, Slanina, Zdenek, Lu, Xing |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7066662/ https://www.ncbi.nlm.nih.gov/pubmed/32190248 http://dx.doi.org/10.1039/c9sc04315b |
Ejemplares similares
-
Crystallographic identification of Eu@C(2n) (2n = 88, 86 and 84): completing a transformation map for existing metallofullerenes
por: Bao, Lipiao, et al.
Publicado: (2018) -
Sc(3)N@I(h)-C(80) as a novel Lewis acid to trap abnormal N-heterocyclic carbenes: the unprecedented formation of a singly bonded [6,6,6]-adduct
por: Chen, Muqing, et al.
Publicado: (2016) -
Highly regioselective complexation of tungsten with Eu@C(82)/Eu@C(84): interplay between endohedral and exohedral metallic units induced by electron transfer
por: Bao, Lipiao, et al.
Publicado: (2019) -
Crystallographic characterization of Lu(2)C(2n) (2n = 76–90): cluster selection by cage size
por: Shen, Wangqiang, et al.
Publicado: (2018) -
A diuranium carbide cluster stabilized inside a C(80) fullerene cage
por: Zhang, Xingxing, et al.
Publicado: (2018)