Cargando…

Light-enabled metal-free pinacol coupling by hydrazine

Efficient carbon–carbon bond formation is of great importance in modern organic synthetic chemistry. The pinacol coupling discovered over a century ago is still one of the most efficient coupling reactions to build the C–C bond in one step. However, traditional pinacol coupling often requires over-s...

Descripción completa

Detalles Bibliográficos
Autores principales:	Qiu, Zihang, Pham, Hanh D. M., Li, Jianbin, Li, Chen-Chen, Castillo-Pazos, Durbis J., Khaliullin, Rustam Z., Li, Chao-Jun
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7066673/ https://www.ncbi.nlm.nih.gov/pubmed/32190250 http://dx.doi.org/10.1039/c9sc03737c

Ejemplares similares

Direct conversion of phenols into primary anilines with hydrazine catalyzed by palladium
por: Qiu, Zihang, et al.
Publicado: (2019)

Metal-free thermal organocatalytic pinacol coupling of arylaldehydes using an isonicotinate catalyst with bis(pinacolato)diboron
por: Yasui, Masamichi, et al.
Publicado: (2021)

Synthesis of α-(perfluoroalkylsulfonyl)propiophenones: a new set of reagents for the light-mediated perfluoroalkylation of aromatics
por: Castillo-Pazos, Durbis J, et al.
Publicado: (2022)

Pinacol-Derived Chlorohydrosilane in Metal-Free Reductive Amination for the Preparation of Tertiary Alkylphenolmethyl Amines
por: Assoah, Benedicta, et al.
Publicado: (2019)

Light-driven transition-metal-free direct decarbonylation of unstrained diaryl ketones via a dual C–C bond cleavage
por: Cao, Dawei, et al.
Publicado: (2022)

EDA mediated S–N bond coupling of nitroarenes and sodium sulfinate salts
por: Lasso, Juan D., et al.
Publicado: (2022)

Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media
por: Chen, Yunhua, et al.
Publicado: (2008)

Empowering alcohols as carbonyl surrogates for Grignard-type reactions
por: Li, Chen-Chen, et al.
Publicado: (2020)

Diastereoselective and enantioselective photoredox pinacol coupling promoted by titanium complexes with a red-absorbing organic dye
por: Calogero, Francesco, et al.
Publicado: (2022)

Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles
por: Jana, Navendu, et al.
Publicado: (2014)

Synthesis of Dihydropyridine Spirocycles by Semi-Pinacol-Driven Dearomatization of Pyridines
por: Abell, Joseph C., et al.
Publicado: (2023)

Assignment of the Crystal Structure to the Aza-Pinacol Coupling Product by X-ray Diffraction and Density Functional Theory Modeling
por: Savateev, Oleksandr, et al.
Publicado: (2022)

Diacetyl as a “traceless” visible light photosensitizer in metal-free cross-dehydrogenative coupling reactions
por: Huang, Chia-Yu, et al.
Publicado: (2019)

Direct deoxygenative borylation of carboxylic acids
por: Li, Jianbin, et al.
Publicado: (2021)

Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State
por: Rashidi-Ranjbar, Parviz, et al.
Publicado: (2001)

Triarylamines as catalytic donors in light-mediated electron donor–acceptor complexes
por: Castillo-Pazos, Durbis J., et al.
Publicado: (2023)

Aryl nitrile oxide cycloaddition reactions in the presence of pinacol boronic acid ester
por: Harding, Sarah L, et al.
Publicado: (2012)

Catalytic protodeboronation of pinacol boronic esters: formal anti-Markovnikov hydromethylation of alkenes
por: Clausen, Florian, et al.
Publicado: (2019)

Metal-free C–H arylation of imidazoheterocycles with aryl hydrazines
por: Jana, Sourav, et al.
Publicado: (2018)

Selective and Serial Suzuki–Miyaura Reactions of Polychlorinated Aromatics with Alkyl Pinacol Boronic Esters
por: Laulhé, Sébastien, et al.
Publicado: (2016)

Spectral data for the synthesis of (E)-alkenylboronic acid pinacol esters via hydroboration of alkynes
por: Gioia, Bruna, et al.
Publicado: (2020)

Synthesis, Molecular Docking Analysis, and Evaluation of Antibacterial and Antioxidant Properties of Stilbenes and Pinacol of Quinolines
por: Digafie, Zeleke, et al.
Publicado: (2021)

Energy-saving hydrogen production by chlorine-free hybrid seawater splitting coupling hydrazine degradation
por: Sun, Fu, et al.
Publicado: (2021)

Crystal structure of hydrazine iron(III) phosphate, the first transition metal phosphate containing hydrazine
por: David, Renald
Publicado: (2015)

N(2)H(4) as traceless mediator for homo- and cross- aryl coupling
por: Lv, Leiyang, et al.
Publicado: (2018)

Mechanochemical Studies on Coupling of Hydrazines and Hydrazine Amides with Phenolic and Furanyl Aldehydes—Hydrazones with Antileishmanial and Antibacterial Activities
por: Kapusterynska, Anna, et al.
Publicado: (2023)

Predictable incorporation of nitrogen into carbon dots: insights from pinacol rearrangement and iminium ion cyclization
por: Cho, Soohyun, et al.
Publicado: (2023)

Radical difluoromethylthiolation of aromatics enabled by visible light
por: Li, Jianbin, et al.
Publicado: (2018)

Suzuki-Type Cross-Coupling Reaction of Unprotected 3-Iodoindazoles with Pinacol Vinyl Boronate: An Expeditive C-3 Vinylation of Indazoles under Microwave Irradiation
por: Vera, Gonzalo, et al.
Publicado: (2018)

Redox-neutral ortho-C–H amination of pinacol arylborates via palladium(ii)/norbornene catalysis for aniline synthesis
por: Chen, Shuqing, et al.
Publicado: (2019)

Liquid metal enabled conformal electronics
por: Ping, Bingyi, et al.
Publicado: (2023)

Large optical nonlinearity enabled by coupled metallic quantum wells
por: Qian, Haoliang, et al.
Publicado: (2019)

Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes
por: Li, Xiaojuan, et al.
Publicado: (2021)

Coupled reaction equilibria enable the light-driven formation of metal-functionalized molecular vanadium oxides
por: Repp, Stefan, et al.
Publicado: (2023)

A ligand-enabled metallaphotoredox protocol for Suzuki-Miyaura cross-couplings for the synthesis of diarylmethanes
por: Li, Jianbin, et al.
Publicado: (2022)

Metal-free oxidative cross-coupling enabled practical synthesis of atropisomeric QUINOL and its derivatives
por: Jiang, Peng-Ying, et al.
Publicado: (2021)

Covalency of hydrogen bonds in liquid water can be probed by proton nuclear magnetic resonance experiments
por: Elgabarty, Hossam, et al.
Publicado: (2015)

A Hydrazine Coupled Cycling Assay Validates the Decrease in Redox Ratio under Starvation in Drosophila
por: Zhu, Chen-Tseh, et al.
Publicado: (2012)

Umpolung carbonyls enable direct allylation and olefination of carbohydrates
por: Kan, Jian, et al.
Publicado: (2022)

Free radical-mediated activation of hydrazine derivatives.
por: Kalyanaraman, B, et al.
Publicado: (1985)

Cannot write session to /tmp/vufind_sessions/sess_7778qk1bgb5tp5hugs18o5juft