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Selenophosphoramide-catalyzed diamination and oxyamination of alkenes

A new selenophosphoramide-catalyzed diamination of terminal- and trans-1,2-disubstituted olefins is presented. Key to the success of this transformation was the introduction of a fluoride scavenger, trimethylsilyl trifluoromethanesulfonate (TMSOTf), to prevent a competitive syn-elimination pathway,...

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Detalles Bibliográficos
Autores principales:	Tabor, John R., Obenschain, Derek C., Michael, Forrest E.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069249/ https://www.ncbi.nlm.nih.gov/pubmed/32206288 http://dx.doi.org/10.1039/c9sc05335b

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