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Unexpected Reaction Pathway of the Alpha-Aminoalkyl Radical Derived from One-Electron Oxidation of S-Alkylglutathiones

Laser flash photolysis and high-resolution mass spectrometry were used to investigate the mechanism of one-electron oxidation of two S-alkylglutathiones using 3-carboxybenzophenone (3CB) as a photosensitizer. This report indicates an unexpected reaction pathway of the α-aminoalkyl radical cation (αN...

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Detalles Bibliográficos
Autores principales: Pedzinski, Tomasz, Bobrowski, Krzysztof, Marciniak, Bronislaw, Filipiak, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070667/
https://www.ncbi.nlm.nih.gov/pubmed/32079230
http://dx.doi.org/10.3390/molecules25040877