Focus on Chemistry of the 10-Dioxane-nido-7,8-dicarba-undecahydrido Undecaborate Zwitterion; Exceptionally Easy Abstraction of Hydrogen Bridge and Double-Action Pathways Observed in Ring Cleavage Reactions with OH(−) as Nucleophile †

Ring cleavage of cyclic ether substituents attached to a boron cage via an oxonium oxygen atom are amongst the most versatile methods for conjoining boron closo-cages with organic functional groups. Here we focus on much less tackled chemistry of the 11-vertex zwitterionic compound [10-(O-(CH(2)-CH(...

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Detalles Bibliográficos
Autores principales: Bakardjiev, Mário, El Anwar, Suzan, Bavol, Dmytro, Růžičková, Zdeňka, Grűner, Bohumír
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070711/
https://www.ncbi.nlm.nih.gov/pubmed/32069968
http://dx.doi.org/10.3390/molecules25040814

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