Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis

Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C–B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide informatio...

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Detalles Bibliográficos
Autores principales: Babu, K. Naresh, Massarwe, Fedaa, Reddy, Reddy Rajasekhar, Eghbarieh, Nadim, Jakob, Manuella, Masarwa, Ahmad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070756/
https://www.ncbi.nlm.nih.gov/pubmed/32093409
http://dx.doi.org/10.3390/molecules25040959
Descripción
Sumario:Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C–B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

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