Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis

Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C–B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide informatio...

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Autores principales: Babu, K. Naresh, Massarwe, Fedaa, Reddy, Reddy Rajasekhar, Eghbarieh, Nadim, Jakob, Manuella, Masarwa, Ahmad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070756/
https://www.ncbi.nlm.nih.gov/pubmed/32093409
http://dx.doi.org/10.3390/molecules25040959
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author Babu, K. Naresh
Massarwe, Fedaa
Reddy, Reddy Rajasekhar
Eghbarieh, Nadim
Jakob, Manuella
Masarwa, Ahmad
author_facet Babu, K. Naresh
Massarwe, Fedaa
Reddy, Reddy Rajasekhar
Eghbarieh, Nadim
Jakob, Manuella
Masarwa, Ahmad
author_sort Babu, K. Naresh
collection PubMed
description Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C–B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.
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spelling pubmed-70707562020-03-19 Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis Babu, K. Naresh Massarwe, Fedaa Reddy, Reddy Rajasekhar Eghbarieh, Nadim Jakob, Manuella Masarwa, Ahmad Molecules Review Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C–B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes. MDPI 2020-02-20 /pmc/articles/PMC7070756/ /pubmed/32093409 http://dx.doi.org/10.3390/molecules25040959 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Babu, K. Naresh
Massarwe, Fedaa
Reddy, Reddy Rajasekhar
Eghbarieh, Nadim
Jakob, Manuella
Masarwa, Ahmad
Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis
title Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis
title_full Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis
title_fullStr Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis
title_full_unstemmed Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis
title_short Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis
title_sort unsymmetrical 1,1-bisboryl species: valuable building blocks in synthesis
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070756/
https://www.ncbi.nlm.nih.gov/pubmed/32093409
http://dx.doi.org/10.3390/molecules25040959
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