Ultra-Uniform and Very Thin Ag Nanowires Synthesized via the Synergy of Cl(−), Br(−) and Fe(3+) for Transparent Conductive Films

The properties and applications of Ag nanowires (AgNWs) are closely related to their morphology and composition. Therefore, controlling the growth process of AgNWs is of great significance for technological applications and fundamental research. Here, silver nanowires (AgNWs) were synthesized via a typical polyol method with the synergistic effect of Cl(−), Br(−), and Fe(3+) mediated agents. The synergistic impact of these mediated agents was investigated intensively, revealing that trace Fe(3+) ions provided selective etching and hindered the strong etching effect from Cl(−) and Br(−) ions. Controlling this synergy allowed the obtainment of highly uniform AgNWs with sub-30 nm diameter and an aspect ratio of over 3000. Transparent conductive films (TCFs) based on these AgNWs without any post-treatment showed a very low sheet resistance of 4.7 Ω sq(−1), a low haze of 1.08% at a high optical transmittance of 95.2% (at 550 nm), and a high figure of merit (FOM) of 1210. TCFs exhibited a robust electrical performance with almost unchanged resistance after 2500 bending cycles. These excellent high-performance characteristics demonstrate the enormous potential of our AgNWs in the field of flexible and transparent materials.