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Fluoroalkyl Pentacarbonylmanganese(I) Complexes as Initiators for the Radical (co)Polymerization of Fluoromonomers

The use of [Mn(R(F))(CO)(5)] (R(F) = CF(3), CHF(2), CH(2)CF(3,) COCF(2)CH(3)) to initiate the radical polymerization of vinylidene fluoride (F(2)C=CH(2), VDF) and the radical alternating copolymerization of vinyl acetate (CH(2)=CHOOCCH(3), VAc) with tert-butyl 2-(trifluoromethyl)acrylate (MAF-TBE) b...

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Detalles Bibliográficos
Autores principales: Morales-Cerrada, Roberto, Ladmiral, Vincent, Gayet, Florence, Fliedel, Christophe, Poli, Rinaldo, Améduri, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7077403/
https://www.ncbi.nlm.nih.gov/pubmed/32046342
http://dx.doi.org/10.3390/polym12020384