Synthesis of Reactive Water-Soluble Narrow-Band-Gap Polymers for Post-Crosslinking

In this study, water-soluble, narrow-band-gap polymers containing reactive groups were prepared by the addition-condensation of pyrrole (Pyr), benzaldehyde-2-sulfonic acid sodium salt (BS), and terephthalaldehydic acid (TPA) or p-hydroxybenzaldehyde (p-HB). TPA and p-HB were used for the post-crosslinking reaction between polymers. The polymers were characterized by employing various analyses such as (1)H-NMR, thermal gravimetric analysis (TGA), and UV-Vis-NIR. The E(g) values of polymers estimated from the absorption edges were 0.55 and 0.62 eV. The post-crosslinking reaction is important for preventing resolubilization and for developing an electron conducting route between the polymer chains. Herein, the post-crosslinked polymer was observed to maintain its narrow-band-gap and conductivity was increased 46 times compared to that observed before crosslinking.