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Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures
In this paper, we studied the alteration of viscoelastic properties of a neat poly(methyl methacrylate) (PMMA), induced by an applied external electric field. The rheological properties of PMMA are measured using a rotational rheometer at elevated temperatures. The electric field effect on the shear...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7077492/ https://www.ncbi.nlm.nih.gov/pubmed/32033328 http://dx.doi.org/10.3390/polym12020335 |
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author | Huo, Miao Guo, Yunlong |
author_facet | Huo, Miao Guo, Yunlong |
author_sort | Huo, Miao |
collection | PubMed |
description | In this paper, we studied the alteration of viscoelastic properties of a neat poly(methyl methacrylate) (PMMA), induced by an applied external electric field. The rheological properties of PMMA are measured using a rotational rheometer at elevated temperatures. The electric field effect on the shear resistance of the polymer was studied by examining rheological responses under difference experimental scenarios. We find that the external electric field can remarkably enhance shear resistance and prevent flow of PMMA melt, enabling it to behave more predictably at high temperatures. Dynamic rheological analysis illustrates that the external electric field speeds up the recovery of mechanical properties of the PMMA melt after large deformations, whereas the PMMA melt exhibits thixotropic behaviors. The recovery velocity is influenced by the strength of the electric field, specifically, and is found to be proportional to the electric field strength. Our experimental characterization may provide new evidence on the tuning mechanical properties of polymer melts via controlling segmental polarization. |
format | Online Article Text |
id | pubmed-7077492 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-70774922020-03-20 Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures Huo, Miao Guo, Yunlong Polymers (Basel) Article In this paper, we studied the alteration of viscoelastic properties of a neat poly(methyl methacrylate) (PMMA), induced by an applied external electric field. The rheological properties of PMMA are measured using a rotational rheometer at elevated temperatures. The electric field effect on the shear resistance of the polymer was studied by examining rheological responses under difference experimental scenarios. We find that the external electric field can remarkably enhance shear resistance and prevent flow of PMMA melt, enabling it to behave more predictably at high temperatures. Dynamic rheological analysis illustrates that the external electric field speeds up the recovery of mechanical properties of the PMMA melt after large deformations, whereas the PMMA melt exhibits thixotropic behaviors. The recovery velocity is influenced by the strength of the electric field, specifically, and is found to be proportional to the electric field strength. Our experimental characterization may provide new evidence on the tuning mechanical properties of polymer melts via controlling segmental polarization. MDPI 2020-02-05 /pmc/articles/PMC7077492/ /pubmed/32033328 http://dx.doi.org/10.3390/polym12020335 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Huo, Miao Guo, Yunlong Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures |
title | Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures |
title_full | Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures |
title_fullStr | Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures |
title_full_unstemmed | Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures |
title_short | Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures |
title_sort | electric field enhances shear resistance of polymer melts via orientational polarization in microstructures |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7077492/ https://www.ncbi.nlm.nih.gov/pubmed/32033328 http://dx.doi.org/10.3390/polym12020335 |
work_keys_str_mv | AT huomiao electricfieldenhancesshearresistanceofpolymermeltsviaorientationalpolarizationinmicrostructures AT guoyunlong electricfieldenhancesshearresistanceofpolymermeltsviaorientationalpolarizationinmicrostructures |