Enhanced Stability of Li-RHC Embedded in an Adaptive TPX™ Polymer Scaffold

In this work, the possibility of creating a polymer-based adaptive scaffold for improving the hydrogen storage properties of the system 2LiH+MgB(2)+7.5(3TiCl(3)·AlCl(3)) was studied. Because of its chemical stability toward the hydrogen storage material, poly(4-methyl-1-pentene) or in-short TPX(TM)...

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Detalles Bibliográficos
Autores principales: Le, Thi Thu, Pistidda, Claudio, Abetz, Clarissa, Georgopanos, Prokopios, Garroni, Sebastiano, Capurso, Giovanni, Milanese, Chiara, Puszkiel, Julián, Dornheim, Martin, Abetz, Volker, Klassen, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7078616/
https://www.ncbi.nlm.nih.gov/pubmed/32098426
http://dx.doi.org/10.3390/ma13040991
Descripción
Sumario:In this work, the possibility of creating a polymer-based adaptive scaffold for improving the hydrogen storage properties of the system 2LiH+MgB(2)+7.5(3TiCl(3)·AlCl(3)) was studied. Because of its chemical stability toward the hydrogen storage material, poly(4-methyl-1-pentene) or in-short TPX(TM) was chosen as the candidate for the scaffolding structure. The composite system was obtained after ball milling of 2LiH+MgB(2)+7.5(3TiCl(3)·AlCl(3)) and a solution of TPX(TM) in cyclohexane. The investigations carried out over the span of ten hydrogenation/de-hydrogenation cycles indicate that the material containing TPX(TM) possesses a higher degree of hydrogen storage stability.

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