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Polypropylene/ZnO Nanocomposites: Mechanical Properties, Photocatalytic Dye Degradation, and Antibacterial Property

Nanocomposite materials were prepared by compounding polypropylene (PP) with zinc oxide (ZnO) nanoparticles, using a twin-screw extruder. The compound was molded by injection molding to form dumbbell-shaped specimens. The influence of ZnO nanoparticle content on the morphology, mechanical properties...

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Detalles Bibliográficos
Autores principales: Prasert, Ampawan, Sontikaew, Somchoke, Sriprapai, Dilok, Chuangchote, Surawut
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7078909/
https://www.ncbi.nlm.nih.gov/pubmed/32092876
http://dx.doi.org/10.3390/ma13040914
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author Prasert, Ampawan
Sontikaew, Somchoke
Sriprapai, Dilok
Chuangchote, Surawut
author_facet Prasert, Ampawan
Sontikaew, Somchoke
Sriprapai, Dilok
Chuangchote, Surawut
author_sort Prasert, Ampawan
collection PubMed
description Nanocomposite materials were prepared by compounding polypropylene (PP) with zinc oxide (ZnO) nanoparticles, using a twin-screw extruder. The compound was molded by injection molding to form dumbbell-shaped specimens. The influence of ZnO nanoparticle content on the morphology, mechanical properties, chemical structure, photocatalytic activity, and antibacterial properties of the obtained nanocomposites was investigated. The morphological images showed that the ZnO nanoparticles were well distributed in the PP matrix. Characterizations of the mechanical properties and chemical structures before and after sunlight exposure found that at the shortest exposure time, crosslinks could occur in the nanocomposites, which resulted in improved mechanical properties. However, sunlight exposure with the time period longer than 18 weeks caused the reduction of the mechanical properties, due to degradation of the PP matrix. It was found that PP with 2% ZnO could achieve the photocatalytic degradation of methylene blue up to 59%. Moreover, the result of antibacterial tests indicated that the nanocomposites had better antibacterial properties than neat PP.
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spelling pubmed-70789092020-04-21 Polypropylene/ZnO Nanocomposites: Mechanical Properties, Photocatalytic Dye Degradation, and Antibacterial Property Prasert, Ampawan Sontikaew, Somchoke Sriprapai, Dilok Chuangchote, Surawut Materials (Basel) Article Nanocomposite materials were prepared by compounding polypropylene (PP) with zinc oxide (ZnO) nanoparticles, using a twin-screw extruder. The compound was molded by injection molding to form dumbbell-shaped specimens. The influence of ZnO nanoparticle content on the morphology, mechanical properties, chemical structure, photocatalytic activity, and antibacterial properties of the obtained nanocomposites was investigated. The morphological images showed that the ZnO nanoparticles were well distributed in the PP matrix. Characterizations of the mechanical properties and chemical structures before and after sunlight exposure found that at the shortest exposure time, crosslinks could occur in the nanocomposites, which resulted in improved mechanical properties. However, sunlight exposure with the time period longer than 18 weeks caused the reduction of the mechanical properties, due to degradation of the PP matrix. It was found that PP with 2% ZnO could achieve the photocatalytic degradation of methylene blue up to 59%. Moreover, the result of antibacterial tests indicated that the nanocomposites had better antibacterial properties than neat PP. MDPI 2020-02-19 /pmc/articles/PMC7078909/ /pubmed/32092876 http://dx.doi.org/10.3390/ma13040914 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Prasert, Ampawan
Sontikaew, Somchoke
Sriprapai, Dilok
Chuangchote, Surawut
Polypropylene/ZnO Nanocomposites: Mechanical Properties, Photocatalytic Dye Degradation, and Antibacterial Property
title Polypropylene/ZnO Nanocomposites: Mechanical Properties, Photocatalytic Dye Degradation, and Antibacterial Property
title_full Polypropylene/ZnO Nanocomposites: Mechanical Properties, Photocatalytic Dye Degradation, and Antibacterial Property
title_fullStr Polypropylene/ZnO Nanocomposites: Mechanical Properties, Photocatalytic Dye Degradation, and Antibacterial Property
title_full_unstemmed Polypropylene/ZnO Nanocomposites: Mechanical Properties, Photocatalytic Dye Degradation, and Antibacterial Property
title_short Polypropylene/ZnO Nanocomposites: Mechanical Properties, Photocatalytic Dye Degradation, and Antibacterial Property
title_sort polypropylene/zno nanocomposites: mechanical properties, photocatalytic dye degradation, and antibacterial property
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7078909/
https://www.ncbi.nlm.nih.gov/pubmed/32092876
http://dx.doi.org/10.3390/ma13040914
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