Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand

Potassium silanide [KSiH(3)](∞) contains 4.2 wt % of hydrogen and has been intensely studied as hydrogen storage material. The macrocyclic ligand Me(4)TACD (1,4,7,10‐tetramethyl‐1,4,7,10‐tetraaminocyclododecane, L) stabilizes the full range of triphenylsilyl complexes [(L)MSiPh(3)](n) (M=Li–Cs), whi...

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Autores principales: Schuhknecht, Danny, Leich, Valeri, Spaniol, Thomas P., Douair, Iskander, Maron, Laurent, Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7079104/
https://www.ncbi.nlm.nih.gov/pubmed/31943432
http://dx.doi.org/10.1002/chem.202000187
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author Schuhknecht, Danny
Leich, Valeri
Spaniol, Thomas P.
Douair, Iskander
Maron, Laurent
Okuda, Jun
author_facet Schuhknecht, Danny
Leich, Valeri
Spaniol, Thomas P.
Douair, Iskander
Maron, Laurent
Okuda, Jun
author_sort Schuhknecht, Danny
collection PubMed
description Potassium silanide [KSiH(3)](∞) contains 4.2 wt % of hydrogen and has been intensely studied as hydrogen storage material. The macrocyclic ligand Me(4)TACD (1,4,7,10‐tetramethyl‐1,4,7,10‐tetraaminocyclododecane, L) stabilizes the full range of triphenylsilyl complexes [(L)MSiPh(3)](n) (M=Li–Cs), which react with H(2) or PhSiH(3) to form molecular [(L)MSiH(3)](n) that can be isolated in soluble form and fully characterized.
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spelling pubmed-70791042020-03-19 Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand Schuhknecht, Danny Leich, Valeri Spaniol, Thomas P. Douair, Iskander Maron, Laurent Okuda, Jun Chemistry Communications Potassium silanide [KSiH(3)](∞) contains 4.2 wt % of hydrogen and has been intensely studied as hydrogen storage material. The macrocyclic ligand Me(4)TACD (1,4,7,10‐tetramethyl‐1,4,7,10‐tetraaminocyclododecane, L) stabilizes the full range of triphenylsilyl complexes [(L)MSiPh(3)](n) (M=Li–Cs), which react with H(2) or PhSiH(3) to form molecular [(L)MSiH(3)](n) that can be isolated in soluble form and fully characterized. John Wiley and Sons Inc. 2020-02-18 2020-03-02 /pmc/articles/PMC7079104/ /pubmed/31943432 http://dx.doi.org/10.1002/chem.202000187 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Schuhknecht, Danny
Leich, Valeri
Spaniol, Thomas P.
Douair, Iskander
Maron, Laurent
Okuda, Jun
Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand
title Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand
title_full Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand
title_fullStr Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand
title_full_unstemmed Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand
title_short Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand
title_sort alkali metal triphenyl‐ and trihydridosilanides stabilized by a macrocyclic polyamine ligand
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7079104/
https://www.ncbi.nlm.nih.gov/pubmed/31943432
http://dx.doi.org/10.1002/chem.202000187
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