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Visible-light promoted regioselective amination and alkylation of remote C(sp(3))-H bonds

The C-N cross coupling reaction has always been a fundamental task in organic synthesis. However, the direct use of N-H group of aryl amines to generate N-centered radicals which would couple with alkyl radicals to construct C-N bonds is still rare. Here we report a visible light-promoted C-N radica...

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Detalles Bibliográficos
Autores principales:	Guo, Quanping, Peng, Qiang, Chai, Hongli, Huo, Yumei, Wang, Shan, Xu, Zhaoqing
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7081228/ https://www.ncbi.nlm.nih.gov/pubmed/32193371 http://dx.doi.org/10.1038/s41467-020-15167-2

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