Experimental and Theoretical Study on the Gas-Phase Reactions of Germyl Radicals with NF(3): Homolytic Substitution at the Nitrogen Atom vs Fluorine Abstraction

[Image: see text] In this paper, we report on the unexplored reaction mechanisms of bimolecular homolytic substitution (S(H)2) between GeH(3) radicals and the nitrogen atom of NF(3). The S(H)2 reactions are studied both experimentally and theoretically with ab initio and density functional theory (D...

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Detalles Bibliográficos
Autores principales: Antoniotti, Paola, Benzi, Paola, Marabello, Domenica, Rosso, Daniele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7081285/
https://www.ncbi.nlm.nih.gov/pubmed/32201776
http://dx.doi.org/10.1021/acsomega.9b03729

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7081285/
https://www.ncbi.nlm.nih.gov/pubmed/32201776
http://dx.doi.org/10.1021/acsomega.9b03729

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