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Experimental and Theoretical Study on the Gas-Phase Reactions of Germyl Radicals with NF(3): Homolytic Substitution at the Nitrogen Atom vs Fluorine Abstraction
[Image: see text] In this paper, we report on the unexplored reaction mechanisms of bimolecular homolytic substitution (S(H)2) between GeH(3) radicals and the nitrogen atom of NF(3). The S(H)2 reactions are studied both experimentally and theoretically with ab initio and density functional theory (D...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7081285/ https://www.ncbi.nlm.nih.gov/pubmed/32201776 http://dx.doi.org/10.1021/acsomega.9b03729 |