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The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles

Magnetic field effects can provide a handle on steering chemical reactions and manipulating yields. The presence of a magnetic field can influence the energy levels of the active species by interacting with their spin states. Here we demonstrate the effect of a magnetic field on the electrocatalytic...

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Detalles Bibliográficos
Autores principales: Westsson, Emma, Picken, Stephen, Koper, Ger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7082754/
https://www.ncbi.nlm.nih.gov/pubmed/32232025
http://dx.doi.org/10.3389/fchem.2020.00163
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author Westsson, Emma
Picken, Stephen
Koper, Ger
author_facet Westsson, Emma
Picken, Stephen
Koper, Ger
author_sort Westsson, Emma
collection PubMed
description Magnetic field effects can provide a handle on steering chemical reactions and manipulating yields. The presence of a magnetic field can influence the energy levels of the active species by interacting with their spin states. Here we demonstrate the effect of a magnetic field on the electrocatalytic processes taking place on platinum-based nanoparticles in fuel cell conditions. We have identified a shift in the potentials representing hydrogen adsorption and desorption, present in all measurements recorded in the presence of a magnetic field. We argue that the changes in electrochemical behavior are a result of the interactions between the magnetic field and the unpaired spin states of hydrogen.
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spelling pubmed-70827542020-03-30 The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles Westsson, Emma Picken, Stephen Koper, Ger Front Chem Chemistry Magnetic field effects can provide a handle on steering chemical reactions and manipulating yields. The presence of a magnetic field can influence the energy levels of the active species by interacting with their spin states. Here we demonstrate the effect of a magnetic field on the electrocatalytic processes taking place on platinum-based nanoparticles in fuel cell conditions. We have identified a shift in the potentials representing hydrogen adsorption and desorption, present in all measurements recorded in the presence of a magnetic field. We argue that the changes in electrochemical behavior are a result of the interactions between the magnetic field and the unpaired spin states of hydrogen. Frontiers Media S.A. 2020-03-12 /pmc/articles/PMC7082754/ /pubmed/32232025 http://dx.doi.org/10.3389/fchem.2020.00163 Text en Copyright © 2020 Westsson, Picken and Koper. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Westsson, Emma
Picken, Stephen
Koper, Ger
The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles
title The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles
title_full The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles
title_fullStr The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles
title_full_unstemmed The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles
title_short The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles
title_sort effect of magnetic field on catalytic properties in core-shell type particles
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7082754/
https://www.ncbi.nlm.nih.gov/pubmed/32232025
http://dx.doi.org/10.3389/fchem.2020.00163
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