Humidity-Resistive Optical NO Gas Sensor Devices Based on Cobalt Tetraphenylporphyrin Dispersed in Hydrophobic Polymer Matrix

We report on an optical nitrogen oxide (NO) gas sensor device using cobalt tetraphenylporphyrin (CoTPP) dispersed in three kinds of hydrophobic polymer film matrix (polystyrene (PSt), ethylcellulose (EC), and polycyclohexyl methacrylate (PCHMA)) to improve humidity resistance. Our approach is very e...

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Detalles Bibliográficos
Autores principales: Shiba, Shunsuke, Yamada, Kohei, Matsuguchi, Masanobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7085509/
https://www.ncbi.nlm.nih.gov/pubmed/32120957
http://dx.doi.org/10.3390/s20051295
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author Shiba, Shunsuke
Yamada, Kohei
Matsuguchi, Masanobu
author_facet Shiba, Shunsuke
Yamada, Kohei
Matsuguchi, Masanobu
author_sort Shiba, Shunsuke
collection PubMed
description We report on an optical nitrogen oxide (NO) gas sensor device using cobalt tetraphenylporphyrin (CoTPP) dispersed in three kinds of hydrophobic polymer film matrix (polystyrene (PSt), ethylcellulose (EC), and polycyclohexyl methacrylate (PCHMA)) to improve humidity resistance. Our approach is very effective because it allows us to achieve not only high humidity resistance, but also a more than sixfold increase in sensitivity compared with CoTPP film due to the high dispersion of CoTPP in the polymer film. The limit of detection was calculated as 33 ppb for the CoTPP-dispersed EC film, which is lower than that of CoTPP film (92 ppb).
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spelling pubmed-70855092020-03-23 Humidity-Resistive Optical NO Gas Sensor Devices Based on Cobalt Tetraphenylporphyrin Dispersed in Hydrophobic Polymer Matrix Shiba, Shunsuke Yamada, Kohei Matsuguchi, Masanobu Sensors (Basel) Communication We report on an optical nitrogen oxide (NO) gas sensor device using cobalt tetraphenylporphyrin (CoTPP) dispersed in three kinds of hydrophobic polymer film matrix (polystyrene (PSt), ethylcellulose (EC), and polycyclohexyl methacrylate (PCHMA)) to improve humidity resistance. Our approach is very effective because it allows us to achieve not only high humidity resistance, but also a more than sixfold increase in sensitivity compared with CoTPP film due to the high dispersion of CoTPP in the polymer film. The limit of detection was calculated as 33 ppb for the CoTPP-dispersed EC film, which is lower than that of CoTPP film (92 ppb). MDPI 2020-02-27 /pmc/articles/PMC7085509/ /pubmed/32120957 http://dx.doi.org/10.3390/s20051295 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Shiba, Shunsuke
Yamada, Kohei
Matsuguchi, Masanobu
Humidity-Resistive Optical NO Gas Sensor Devices Based on Cobalt Tetraphenylporphyrin Dispersed in Hydrophobic Polymer Matrix
title Humidity-Resistive Optical NO Gas Sensor Devices Based on Cobalt Tetraphenylporphyrin Dispersed in Hydrophobic Polymer Matrix
title_full Humidity-Resistive Optical NO Gas Sensor Devices Based on Cobalt Tetraphenylporphyrin Dispersed in Hydrophobic Polymer Matrix
title_fullStr Humidity-Resistive Optical NO Gas Sensor Devices Based on Cobalt Tetraphenylporphyrin Dispersed in Hydrophobic Polymer Matrix
title_full_unstemmed Humidity-Resistive Optical NO Gas Sensor Devices Based on Cobalt Tetraphenylporphyrin Dispersed in Hydrophobic Polymer Matrix
title_short Humidity-Resistive Optical NO Gas Sensor Devices Based on Cobalt Tetraphenylporphyrin Dispersed in Hydrophobic Polymer Matrix
title_sort humidity-resistive optical no gas sensor devices based on cobalt tetraphenylporphyrin dispersed in hydrophobic polymer matrix
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7085509/
https://www.ncbi.nlm.nih.gov/pubmed/32120957
http://dx.doi.org/10.3390/s20051295
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AT matsuguchimasanobu humidityresistiveopticalnogassensordevicesbasedoncobalttetraphenylporphyrindispersedinhydrophobicpolymermatrix

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