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Impedimetric Detection of Ammonia and Low Molecular Weight Amines in the Gas Phase with Covalent Organic Frameworks

Two Covalent Organic Frameworks (COF), named TFP-BZ and TFP-DMBZ, were synthesized using the imine condensation between 1,3,5-triformylphloroglucinol (TFP) with benzidine (BZ) or 3,3-dimethylbenzidine (DMBZ). These materials were deposited, such as films over interdigitated electrodes (IDE), by chem...

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Autores principales: Rodríguez, Andrés, Rico, Elio, Sierra, Cesar, Rodríguez, Oscar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7085617/
https://www.ncbi.nlm.nih.gov/pubmed/32138323
http://dx.doi.org/10.3390/s20051385
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author Rodríguez, Andrés
Rico, Elio
Sierra, Cesar
Rodríguez, Oscar
author_facet Rodríguez, Andrés
Rico, Elio
Sierra, Cesar
Rodríguez, Oscar
author_sort Rodríguez, Andrés
collection PubMed
description Two Covalent Organic Frameworks (COF), named TFP-BZ and TFP-DMBZ, were synthesized using the imine condensation between 1,3,5-triformylphloroglucinol (TFP) with benzidine (BZ) or 3,3-dimethylbenzidine (DMBZ). These materials were deposited, such as films over interdigitated electrodes (IDE), by chemical bath deposition, giving rise to TFP-BZ-IDE and TFP-DMBZ-IDE systems. The synthesized COFs powders were characterized by Powder X-Ray Diffraction (PXRD), Fourier Transform Infrared spectroscopy (FT-IR), solid-state Nuclear Magnetic Resonance (ssNMR), nitrogen adsorption isotherms, Scanning Electron Microscopy (SEM), and Raman spectroscopy, while the films were characterized by SEM and Raman. Ammonia and low molecular weight amine sensing were developed with the COF film systems using the impedance electrochemical spectroscopy (EIS). Results showed that the systems TFP-BZ-IDE and TFP-DMBZ-IDE detect low molecular weight amines selectively by impedimetric analysis. Remarkably, with no significant interference by other atmospheric gas compounds such as nitrogen, carbon dioxide, and methane. Additionally, both COF films presented a range of sensitivity at low amine concentrations below two ppm at room temperature.
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spelling pubmed-70856172020-04-21 Impedimetric Detection of Ammonia and Low Molecular Weight Amines in the Gas Phase with Covalent Organic Frameworks Rodríguez, Andrés Rico, Elio Sierra, Cesar Rodríguez, Oscar Sensors (Basel) Article Two Covalent Organic Frameworks (COF), named TFP-BZ and TFP-DMBZ, were synthesized using the imine condensation between 1,3,5-triformylphloroglucinol (TFP) with benzidine (BZ) or 3,3-dimethylbenzidine (DMBZ). These materials were deposited, such as films over interdigitated electrodes (IDE), by chemical bath deposition, giving rise to TFP-BZ-IDE and TFP-DMBZ-IDE systems. The synthesized COFs powders were characterized by Powder X-Ray Diffraction (PXRD), Fourier Transform Infrared spectroscopy (FT-IR), solid-state Nuclear Magnetic Resonance (ssNMR), nitrogen adsorption isotherms, Scanning Electron Microscopy (SEM), and Raman spectroscopy, while the films were characterized by SEM and Raman. Ammonia and low molecular weight amine sensing were developed with the COF film systems using the impedance electrochemical spectroscopy (EIS). Results showed that the systems TFP-BZ-IDE and TFP-DMBZ-IDE detect low molecular weight amines selectively by impedimetric analysis. Remarkably, with no significant interference by other atmospheric gas compounds such as nitrogen, carbon dioxide, and methane. Additionally, both COF films presented a range of sensitivity at low amine concentrations below two ppm at room temperature. MDPI 2020-03-03 /pmc/articles/PMC7085617/ /pubmed/32138323 http://dx.doi.org/10.3390/s20051385 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Rodríguez, Andrés
Rico, Elio
Sierra, Cesar
Rodríguez, Oscar
Impedimetric Detection of Ammonia and Low Molecular Weight Amines in the Gas Phase with Covalent Organic Frameworks
title Impedimetric Detection of Ammonia and Low Molecular Weight Amines in the Gas Phase with Covalent Organic Frameworks
title_full Impedimetric Detection of Ammonia and Low Molecular Weight Amines in the Gas Phase with Covalent Organic Frameworks
title_fullStr Impedimetric Detection of Ammonia and Low Molecular Weight Amines in the Gas Phase with Covalent Organic Frameworks
title_full_unstemmed Impedimetric Detection of Ammonia and Low Molecular Weight Amines in the Gas Phase with Covalent Organic Frameworks
title_short Impedimetric Detection of Ammonia and Low Molecular Weight Amines in the Gas Phase with Covalent Organic Frameworks
title_sort impedimetric detection of ammonia and low molecular weight amines in the gas phase with covalent organic frameworks
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7085617/
https://www.ncbi.nlm.nih.gov/pubmed/32138323
http://dx.doi.org/10.3390/s20051385
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