Ultraviolet photolysis of H(2)S and its implications for SH radical production in the interstellar medium

Hydrogen sulfide radicals in the ground state, SH(X), and hydrogen disulfide molecules, H(2)S, are both detected in the interstellar medium, but the returned SH(X)/H(2)S abundance ratios imply a depletion of the former relative to that predicted by current models (which assume that photon absorption by H(2)S at energies below the ionization limit results in H + SH photoproducts). Here we report that translational spectroscopy measurements of the H atoms and S((1)D) atoms formed by photolysis of jet-cooled H(2)S molecules at many wavelengths in the range 122 ≤ λ ≤155 nm offer a rationale for this apparent depletion; the quantum yield for forming SH(X) products, Γ, decreases from unity (at the longest excitation wavelengths) to zero at short wavelengths. Convoluting the wavelength dependences of Γ, the H(2)S parent absorption and the interstellar radiation field implies that only ~26% of photoexcitation events result in SH(X) products. The findings suggest a need to revise the relevant astrochemical models.