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δ and φ back-donation in An(IV) metallacycles

In all known examples of metal–ligand (M–L) δ and φ bonds, the metal orbitals are aligned to the ligand orbitals in a “head-to-head” or “side-to-head” fashion. Here, we report two fundamentally new types of M–L δ and φ interactions; “head-to-side” δ and “side-to-side” φ back-bonding, found in comple...

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Detalles Bibliográficos
Autores principales: Kelley, Morgan P., Popov, Ivan A., Jung, Julie, Batista, Enrique R., Yang, Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7096508/
https://www.ncbi.nlm.nih.gov/pubmed/32214090
http://dx.doi.org/10.1038/s41467-020-15197-w

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