Cargando…

Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting

Water splitting is thermodynamically uphill reaction, hence it cannot occur easily, and also highly complicated and challenging reaction in chemistry. In electrocatalytic water splitting, the combination of oxygen and hydrogen evolution reactions produces highly clean and sustainable hydrogen energy...

Descripción completa

Detalles Bibliográficos
Autores principales: Arumugam, Sivaranjani, Toku, Yuhki, Ju, Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7096520/
https://www.ncbi.nlm.nih.gov/pubmed/32214145
http://dx.doi.org/10.1038/s41598-020-62259-6
Descripción
Sumario:Water splitting is thermodynamically uphill reaction, hence it cannot occur easily, and also highly complicated and challenging reaction in chemistry. In electrocatalytic water splitting, the combination of oxygen and hydrogen evolution reactions produces highly clean and sustainable hydrogen energy and which attracts research communities. Also, fabrication of highly active and low cost materials for water splitting is a major challenge. Therefore, in the present study, γ-Fe(2)O(3) nanowires were fabricated from highly available and cost-effective iron plate without any chemical modifications/doping onto the surface of the working electrode with high current density. The fabricated nanowires achieved the current density of 10 mA/cm(2) at 1.88 V vs. RHE with the scan rate of 50 mV/sec. Stability measurements of the fabricated Fe(2)O(3) nanowires were monitored up to 3275 sec with the current density of 9.6 mA/cm(2) at a constant potential of 1.7 V vs. RHE and scan rate of 50 mV/sec.