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Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting
Water splitting is thermodynamically uphill reaction, hence it cannot occur easily, and also highly complicated and challenging reaction in chemistry. In electrocatalytic water splitting, the combination of oxygen and hydrogen evolution reactions produces highly clean and sustainable hydrogen energy...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7096520/ https://www.ncbi.nlm.nih.gov/pubmed/32214145 http://dx.doi.org/10.1038/s41598-020-62259-6 |
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author | Arumugam, Sivaranjani Toku, Yuhki Ju, Yang |
author_facet | Arumugam, Sivaranjani Toku, Yuhki Ju, Yang |
author_sort | Arumugam, Sivaranjani |
collection | PubMed |
description | Water splitting is thermodynamically uphill reaction, hence it cannot occur easily, and also highly complicated and challenging reaction in chemistry. In electrocatalytic water splitting, the combination of oxygen and hydrogen evolution reactions produces highly clean and sustainable hydrogen energy and which attracts research communities. Also, fabrication of highly active and low cost materials for water splitting is a major challenge. Therefore, in the present study, γ-Fe(2)O(3) nanowires were fabricated from highly available and cost-effective iron plate without any chemical modifications/doping onto the surface of the working electrode with high current density. The fabricated nanowires achieved the current density of 10 mA/cm(2) at 1.88 V vs. RHE with the scan rate of 50 mV/sec. Stability measurements of the fabricated Fe(2)O(3) nanowires were monitored up to 3275 sec with the current density of 9.6 mA/cm(2) at a constant potential of 1.7 V vs. RHE and scan rate of 50 mV/sec. |
format | Online Article Text |
id | pubmed-7096520 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-70965202020-03-30 Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting Arumugam, Sivaranjani Toku, Yuhki Ju, Yang Sci Rep Article Water splitting is thermodynamically uphill reaction, hence it cannot occur easily, and also highly complicated and challenging reaction in chemistry. In electrocatalytic water splitting, the combination of oxygen and hydrogen evolution reactions produces highly clean and sustainable hydrogen energy and which attracts research communities. Also, fabrication of highly active and low cost materials for water splitting is a major challenge. Therefore, in the present study, γ-Fe(2)O(3) nanowires were fabricated from highly available and cost-effective iron plate without any chemical modifications/doping onto the surface of the working electrode with high current density. The fabricated nanowires achieved the current density of 10 mA/cm(2) at 1.88 V vs. RHE with the scan rate of 50 mV/sec. Stability measurements of the fabricated Fe(2)O(3) nanowires were monitored up to 3275 sec with the current density of 9.6 mA/cm(2) at a constant potential of 1.7 V vs. RHE and scan rate of 50 mV/sec. Nature Publishing Group UK 2020-03-25 /pmc/articles/PMC7096520/ /pubmed/32214145 http://dx.doi.org/10.1038/s41598-020-62259-6 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
spellingShingle | Article Arumugam, Sivaranjani Toku, Yuhki Ju, Yang Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting |
title | Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting |
title_full | Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting |
title_fullStr | Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting |
title_full_unstemmed | Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting |
title_short | Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting |
title_sort | fabrication of γ-fe(2)o(3) nanowires from abundant and low-cost fe plate for highly effective electrocatalytic water splitting |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7096520/ https://www.ncbi.nlm.nih.gov/pubmed/32214145 http://dx.doi.org/10.1038/s41598-020-62259-6 |
work_keys_str_mv | AT arumugamsivaranjani fabricationofgfe2o3nanowiresfromabundantandlowcostfeplateforhighlyeffectiveelectrocatalyticwatersplitting AT tokuyuhki fabricationofgfe2o3nanowiresfromabundantandlowcostfeplateforhighlyeffectiveelectrocatalyticwatersplitting AT juyang fabricationofgfe2o3nanowiresfromabundantandlowcostfeplateforhighlyeffectiveelectrocatalyticwatersplitting |