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Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting

Water splitting is thermodynamically uphill reaction, hence it cannot occur easily, and also highly complicated and challenging reaction in chemistry. In electrocatalytic water splitting, the combination of oxygen and hydrogen evolution reactions produces highly clean and sustainable hydrogen energy...

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Autores principales: Arumugam, Sivaranjani, Toku, Yuhki, Ju, Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7096520/
https://www.ncbi.nlm.nih.gov/pubmed/32214145
http://dx.doi.org/10.1038/s41598-020-62259-6
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author Arumugam, Sivaranjani
Toku, Yuhki
Ju, Yang
author_facet Arumugam, Sivaranjani
Toku, Yuhki
Ju, Yang
author_sort Arumugam, Sivaranjani
collection PubMed
description Water splitting is thermodynamically uphill reaction, hence it cannot occur easily, and also highly complicated and challenging reaction in chemistry. In electrocatalytic water splitting, the combination of oxygen and hydrogen evolution reactions produces highly clean and sustainable hydrogen energy and which attracts research communities. Also, fabrication of highly active and low cost materials for water splitting is a major challenge. Therefore, in the present study, γ-Fe(2)O(3) nanowires were fabricated from highly available and cost-effective iron plate without any chemical modifications/doping onto the surface of the working electrode with high current density. The fabricated nanowires achieved the current density of 10 mA/cm(2) at 1.88 V vs. RHE with the scan rate of 50 mV/sec. Stability measurements of the fabricated Fe(2)O(3) nanowires were monitored up to 3275 sec with the current density of 9.6 mA/cm(2) at a constant potential of 1.7 V vs. RHE and scan rate of 50 mV/sec.
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spelling pubmed-70965202020-03-30 Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting Arumugam, Sivaranjani Toku, Yuhki Ju, Yang Sci Rep Article Water splitting is thermodynamically uphill reaction, hence it cannot occur easily, and also highly complicated and challenging reaction in chemistry. In electrocatalytic water splitting, the combination of oxygen and hydrogen evolution reactions produces highly clean and sustainable hydrogen energy and which attracts research communities. Also, fabrication of highly active and low cost materials for water splitting is a major challenge. Therefore, in the present study, γ-Fe(2)O(3) nanowires were fabricated from highly available and cost-effective iron plate without any chemical modifications/doping onto the surface of the working electrode with high current density. The fabricated nanowires achieved the current density of 10 mA/cm(2) at 1.88 V vs. RHE with the scan rate of 50 mV/sec. Stability measurements of the fabricated Fe(2)O(3) nanowires were monitored up to 3275 sec with the current density of 9.6 mA/cm(2) at a constant potential of 1.7 V vs. RHE and scan rate of 50 mV/sec. Nature Publishing Group UK 2020-03-25 /pmc/articles/PMC7096520/ /pubmed/32214145 http://dx.doi.org/10.1038/s41598-020-62259-6 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Arumugam, Sivaranjani
Toku, Yuhki
Ju, Yang
Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting
title Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting
title_full Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting
title_fullStr Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting
title_full_unstemmed Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting
title_short Fabrication of γ-Fe(2)O(3) Nanowires from Abundant and Low-cost Fe Plate for Highly Effective Electrocatalytic Water Splitting
title_sort fabrication of γ-fe(2)o(3) nanowires from abundant and low-cost fe plate for highly effective electrocatalytic water splitting
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7096520/
https://www.ncbi.nlm.nih.gov/pubmed/32214145
http://dx.doi.org/10.1038/s41598-020-62259-6
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