Cargando…

Secondary structure effects on internal proton transfer in poly-peptides

A pump–probe approach was designed to determine the internal proton transfer (PT) rate in a series of poly-peptide radical cations containing both histidine and tryptophan. The proton transfer is driven by the gas-phase basicity difference between residues. The fragmentation scheme indicates that th...

Descripción completa

Detalles Bibliográficos
Autores principales: Bouakil, M., Chirot, F., Girod, M., Dugourd, P., MacAleese, L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Crystallographic Association 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7100371/
https://www.ncbi.nlm.nih.gov/pubmed/32232075
http://dx.doi.org/10.1063/4.0000003

Ejemplares similares