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Ruthenium‐Catalyzed Hydrogenative Degradation of End‐of‐Life Poly(lactide) to Produce 1,2‐Propanediol as Platform Chemical
The chemical recycling of end‐of‐life polymers can add some value to a future circular economy. In this regard, the hydrogenative degradation of end‐of‐life PLA was investigated to produce 1,2‐propanediol as product, which is a useful building block in polymer chemistry. In more detail, the commerci...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7110137/ https://www.ncbi.nlm.nih.gov/pubmed/32257748 http://dx.doi.org/10.1002/open.202000050 |
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author | Kindler, Tim‐Oliver Alberti, Christoph Fedorenko, Elena Santangelo, Nicolo Enthaler, Stephan |
author_facet | Kindler, Tim‐Oliver Alberti, Christoph Fedorenko, Elena Santangelo, Nicolo Enthaler, Stephan |
author_sort | Kindler, Tim‐Oliver |
collection | PubMed |
description | The chemical recycling of end‐of‐life polymers can add some value to a future circular economy. In this regard, the hydrogenative degradation of end‐of‐life PLA was investigated to produce 1,2‐propanediol as product, which is a useful building block in polymer chemistry. In more detail, the commercially available Ru‐MACHO‐BH complex was applied as catalyst to degrade end‐of‐life PLA efficiently to 1,2‐propanediol under mild conditions. After investigations of the reaction conditions a set of end‐of‐life PLA goods were subjected to degradation. |
format | Online Article Text |
id | pubmed-7110137 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-71101372020-04-02 Ruthenium‐Catalyzed Hydrogenative Degradation of End‐of‐Life Poly(lactide) to Produce 1,2‐Propanediol as Platform Chemical Kindler, Tim‐Oliver Alberti, Christoph Fedorenko, Elena Santangelo, Nicolo Enthaler, Stephan ChemistryOpen Communications The chemical recycling of end‐of‐life polymers can add some value to a future circular economy. In this regard, the hydrogenative degradation of end‐of‐life PLA was investigated to produce 1,2‐propanediol as product, which is a useful building block in polymer chemistry. In more detail, the commercially available Ru‐MACHO‐BH complex was applied as catalyst to degrade end‐of‐life PLA efficiently to 1,2‐propanediol under mild conditions. After investigations of the reaction conditions a set of end‐of‐life PLA goods were subjected to degradation. John Wiley and Sons Inc. 2020-04-01 /pmc/articles/PMC7110137/ /pubmed/32257748 http://dx.doi.org/10.1002/open.202000050 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
spellingShingle | Communications Kindler, Tim‐Oliver Alberti, Christoph Fedorenko, Elena Santangelo, Nicolo Enthaler, Stephan Ruthenium‐Catalyzed Hydrogenative Degradation of End‐of‐Life Poly(lactide) to Produce 1,2‐Propanediol as Platform Chemical |
title | Ruthenium‐Catalyzed Hydrogenative Degradation of End‐of‐Life Poly(lactide) to Produce 1,2‐Propanediol as Platform Chemical |
title_full | Ruthenium‐Catalyzed Hydrogenative Degradation of End‐of‐Life Poly(lactide) to Produce 1,2‐Propanediol as Platform Chemical |
title_fullStr | Ruthenium‐Catalyzed Hydrogenative Degradation of End‐of‐Life Poly(lactide) to Produce 1,2‐Propanediol as Platform Chemical |
title_full_unstemmed | Ruthenium‐Catalyzed Hydrogenative Degradation of End‐of‐Life Poly(lactide) to Produce 1,2‐Propanediol as Platform Chemical |
title_short | Ruthenium‐Catalyzed Hydrogenative Degradation of End‐of‐Life Poly(lactide) to Produce 1,2‐Propanediol as Platform Chemical |
title_sort | ruthenium‐catalyzed hydrogenative degradation of end‐of‐life poly(lactide) to produce 1,2‐propanediol as platform chemical |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7110137/ https://www.ncbi.nlm.nih.gov/pubmed/32257748 http://dx.doi.org/10.1002/open.202000050 |
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